triphenyl-arsane; tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=20°C; Alkylation; 14 h;

1: D4v With triphenyl-arsane; tetrabutyl ammonium fluoride in tetrahydrofuran T=20°C; 0.166667 h; 2: methyl 2-iodobenzoate With bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=20°C; 8 h;

palladium diacetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; trichlorophosphate T=140°C; 20 h; Inert atmosphere;

1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / ethylene glycol dimethyl ether; water / 12 h / Inert atmosphere; Reflux 2.1: trifluoroacetic acid / dichloromethane / 12 h / 20 °C / Inert atmosphere 3.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.5 h / 20 °C / Inert atmosphere; Cooling with ice 3.2: 12 h / 20 °C / Inert atmosphere; Cooling with ice 4.1: lithium hydroxide hydrate / tetrahydrofuran; water / 12 h / 60 °C 4.2: 20 °C 5.1: diphenyl phosphoryl azide; triethylamine / toluene / 0.17 h / 100 °C / Inert atmosphere; Microwave irradiation 6.1: pyridine / dichloromethane / 0.5 h / 20 °C / Inert atmosphere; Cooling with ice 7.1: triethylsilane; 1,3-bis-(diphenylphosphino)propane; palladium diacetate / N,N-dimethyl-formamide / 1 h / 60 °C / Inert atmosphere 8.1: methanol; trifluorormethanesulfonic acid; trimethyl orthoformate / nitromethane / 1 h / 100 °C / Inert atmosphere; Cooling with ice View Scheme

in toluene

C70H44Cl2F64N2O6Pd2; tetrabutylammomium bromide; sodium carbonate in water T=150°C; 0.45 h; Microwave irradiationGreen chemistry; Reagent/catalyst; regioselective reaction;

palladium diacetate; triphenylphosphine; cesium fluoride in N,N-dimethyl-formamide T=100°C; Suzuki-Miyaura coupling; 72 h;

1,4-diaza-bicyclo[2.2.2]octane; palladium 10 on activated carbon in toluene T=120°C; P=4654.46 Torr; 2 h; Autoclave;

zinc; [CoI2(1,2-bis(diphenylphosphino)ethane)] in tetrahydrofuran T=75°C; 24 h;

triethylamine; 1,2-bis-(diphenylphosphino)ethane; zinc; Ni(Br)2(dppe) in acetonitrile T=80°C; 36 h;