in water aq. soln. of potassium oxalate was added to aq. soln. of manganese acetate, stirred for 30 min; solid was isolated, washed with EtOH, dried at 50°C, elem. anal.;
in neat (no solvent, solid phase) Mn(OAc)2*4H2O and (NH4)2C2O4*H2O mixed in 1:1.2 mole ratio; ground (40 min); heated (80°C, several h); washed with distd. H2O; filtered; dried (110°C, 10 h);
参考文献
Yuan, Anbao; Wang, Xiuling; Wang, Yuqin; Hu, Jie
Electrochimica Acta, 2009 , vol. 54, # 3 p. 1021 - 1026
in water Electrochem. Process; electrodeposited from 5 mM Mn(CH3COO)2*4H2O potentiostatically at 1.0 V for 1 min at 25°C in air; washed with DI H2O; dried (85°C) overnight; FE-SEM;
in acetic acid
Kinetics; soln. of AIBN and Mn(OAc)2*4H2O mixed at required conc. at 70°C, AIBN in glacial acetic acid in the presence of O2 served as the source for the radicals;
参考文献
Adamyan; Geletii; Popova; Zakharov
Kinetics and Catalysis, 1991 , vol. 31, # 6 pt 2 p. 1307 - 1310
