(S)-(+)-2-辛醇合成路线 （共 200 条）
反应条件
1: With DMEAD; 4-carboxyphenyldiphenylphosphine in tetrahydrofuran T=20°C; 0.166667 h; 2: With water; sodium hydroxide in tetrahydrofuran T=20°C; stereospecific reaction;
参考文献
Muramoto, Natsuko; Yoshino, Kazuki; Misaki, Tomonori; Sugimura, Takashi
Synthesis (Germany), 2013 , vol. 45, # 7 art. no. SS-2013-F0030-OP, p. 931 - 935
参考文献
Houssa; Phillips
Journal of the Chemical Society, 1932 , p. 111
参考文献
Gerrard
Journal of the Chemical Society, 1944 , p. 85
Journal of the Chemical Society, 1945 , p. 106,110
反应条件
(S)-α-alanine; pyridoxal 5'-phosphate; nicotinamide adenine dinucleotide; ammonium formate; alcohol dehydrogenase; lactate dehydrogenase in aq. phosphate buffer T=30°C; pH=7.5; 24 h; Enzymatic reaction;
参考文献
Chemistry - A European Journal, , vol. 19, # 12 p. 4030 - 4035
反应条件
1: HI 2: diluted methanol; sodium azide / 90 °C 3: PtO2; methanol / 2206.5 Torr / Hydrogenation View Scheme
参考文献
Levene; Rothen
Journal of Biological Chemistry, 1936 , vol. 115, p. 426
反应条件
partiell (65prozent) racemisches Praeparat (das Edukt ist partiell racemisch);
参考文献
Sakamoto, Izumi; Izumi, Norimasa; Yamada, Taeko; Tsunoda, Tetsuto
Organic Letters, 2006 , vol. 8, # 1 p. 71 - 74
反应条件
1: NOCl 2: 100 °C / bei 8-taegigen Erhitzen im Kohlendioxydstrom View Scheme
参考文献
Yang, Yi; Liu, Ji; Li, Zhi
Angewandte Chemie - International Edition, 2014 , vol. 53, # 12 p. 3120 - 3124
Angew. Chem., 2014 , vol. 126, # 12 p. 3348,1
反应条件
(S)-α-alanine; pyridoxal 5'-phosphate; nicotinamide adenine dinucleotide; ammonium formate; alcohol dehydrogenase; lactate dehydrogenase in aq. phosphate buffer T=30°C; pH=7.5; 24 h; Enzymatic reaction;
参考文献
Chemistry - A European Journal, , vol. 19, # 12 p. 4030 - 4035
反应条件
dipotassium hydrogenphosphate; phosphoric acid; EC 1.1.1.2 ketoreductase in hexane T=25°C; pH=7.3; 168 h; Equilibrium constant; Further Variations:Solvents;
参考文献
Tewari, Yadu B.; Schantz, Michele M.; Phinney, Karen W.; Rozzell, J. David
Journal of Chemical Thermodynamics, 2005 , vol. 37, # 1 p. 89 - 96
参考文献
Chemische Berichte, , vol. 92, p. 370,376
