(S)-(+)-2-辛醇合成路线 （共 200 条）
反应条件
NADPH; P450 BM3 mutation of F87V/A328F enzyme in dimethyl sulfoxide pH=7.5; aq. phosphate bufferEnzymatic reaction; optical yield given as percent eeregioselective reaction;
参考文献
Chemical Communications, , vol. 47, # 3 p. 944 - 946
反应条件
His-tagged Pseudomonas sp. metallo-β-lactamase-type alkylsulfatase Pisa1; water; tris(hydroxymethyl)methylamine hydrochloride T=30°C; pH=8.2; 6 h; Resolution of racemateEnzymatic reaction; optical yield given as percent eestereoselective reaction;
参考文献
Organic Letters, , vol. 13, # 16 p. 4296 - 4299
反应条件
D-glucopyranose in aq. phosphate buffer; dimethyl sulfoxide T=30°C; pH=8; 4 h; Reagent/catalyst; enantioselective reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 12 p. 3120 - 3124
Angew. Chem., , vol. 126, # 12 p. 3348,1
反应条件
complex from (4R,5R)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane and tris(isopropoxy)chlorotitane in tetrahydrofuran T=-50°C; Yield given. Yields of byproduct given;
参考文献
Helvetica Chimica Acta, , vol. 70, p. 954 - 974
反应条件
Pseudomonas cepacia lipase in di-isopropyl ether T=30°C; Esterification; Racemate separation; 16 h;
参考文献
Synlett, , # 2 p. 225 - 226
反应条件
1: H2SO4 / methanol / 0.5 h / -10 - 0 °C 2: H2 View Scheme
参考文献
Journal of Organic Chemistry, , vol. 51, # 24 p. 4728 - 4731
反应条件
Lipase Amano AK T=20°C; pH=7; 72 h; aq. phosphate bufferEnzymatic reaction;
参考文献
Journal of Molecular Catalysis B: Enzymatic, , vol. 72, # 3-4 p. 270 - 275
反应条件
D-glucopyranose in aq. phosphate buffer; dimethyl sulfoxide T=30°C; pH=8; 4 h; Reagent/catalyst; enantioselective reaction;
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 12 p. 3120 - 3124
Angew. Chem., , vol. 126, # 12 p. 3348,1
反应条件
sodium in diethyl ether 96 h; Ambient temperature;
参考文献
Tetrahedron, , vol. 45, # 2 p. 507 - 516
