反式-11-十八烯酸甲酯合成路线 （共 27 条）
反应条件
in methanol; diethyl ether; toluene T=20°C; 0.5 h;
参考文献
Biochemistry, , vol. 51, # 40 p. 7880 - 7890
参考文献
Journal of the Chemical Society [Section] C: Organic, , p. 1984 - 1997
反应条件
potassium tert-butylate 1.) DMF, 20 deg C, 3h, 2.) 5h; Yield given. Multistep reaction;
参考文献
Chemistry of Natural Compounds, , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, , vol. 16, # 1 p. 97 - 102
反应条件
sodium hexamethyldisilazane 1) THF, room temperature, 30 min, reflux, 1 h; 2) -78 --> 20 deg C, overnight (room temperature); Yield given. Multistep reaction;
参考文献
Russian Chemical Bulletin, , vol. 43, # 6 p. 1079 - 1080
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 6 p. 1141 - 1142
反应条件
1: (i) NaI, (ii) /BRN= 610776/ 2: (i) NaOEt, (ii) /BRN= 1560236/, (iii) aq. NaOH View Scheme
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 32, # 6 p. 1802 - 1807,1785 - 1789
参考文献
Vaver,V.A. et al.
Chemistry of Natural Compounds, 1970 , vol. 6, p. 167 - 169
Khimiya Prirodnykh Soedinenii, 1970 , vol. 6, # 2 p. 170 - 173
反应条件
1: LiAlH4 / diethyl ether / 3 h / Heating
2: pyridine / 10 h / Ambient temperature
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
