4-正丙基-1-庚基-4-醇合成路线 （共 18 条）
反应条件
boron trifluoride diethyl etherate
参考文献
Naruta,Y. et al.
Chemistry Letters, 1979 , p. 919 - 922
参考文献
Slobodin
Zhurnal Obshchei Khimii, 1938 , vol. 8, p. 245,250
Chem. Zentralbl., 1939 , vol. 110, # II p. 66
参考文献
Saizew,P.; Saizew,A.
Justus Liebigs Annalen der Chemie, 1879 , vol. 196, p. 109
反应条件
cyclohexanone
further reagent: heptan-2-one; Yield given;
参考文献
Reetz, Manfred T.; Westermann, Juergen; Steinbach, Rainer; Wenderoth, Bernd; Peter, Roland; et al.
Chemische Berichte, 1985 , vol. 118, # 4 p. 1421 - 1440
反应条件
heptan-2-one
further reagent: cyclohexanone; Yield given;
参考文献
Reetz, Manfred T.; Westermann, Juergen; Steinbach, Rainer; Wenderoth, Bernd; Peter, Roland; et al.
Chemische Berichte, 1985 , vol. 118, # 4 p. 1421 - 1440
反应条件
Ti(NMe2)4
multistep reaction; selectivity of Ti(NMe2)4 as protective agent for carbonyl compounds (preferential protection of heptan-2-one); competition between heptan-2-one and dipropylketone;
参考文献
Reetz, Manfred T.; Wenderoth, Bernd; Peter, Roland
Journal of the Chemical Society, Chemical Communications, 1983 , # 8 p. 406 - 408
反应条件
Ti(NMe2)4
multistep reaction; selectivity of Ti(NMe2)4 as protective agent for carbonyl compounds (preferential protection of cyclohexanone); competition between cyclic and acyclic ketone;
参考文献
Reetz, Manfred T.; Wenderoth, Bernd; Peter, Roland
Journal of the Chemical Society, Chemical Communications, 1983 , # 8 p. 406 - 408
反应条件
hydrogen; platinum(IV) oxide; ruthenium in dichloromethane
T=20°C; P=760.051 Torr;
参考文献
Cossy, Janine; Bargiggia, Frederic; BouzBouz, Samir
Organic Letters, 2003 , vol. 5, # 4 p. 459 - 462
