1-碘基-3,5-二硝基苯合成路线 （共 23 条）
参考文献
Case
Journal of the American Chemical Society, 1942 , vol. 64, p. 1848,1850, 1851
反应条件
sodium acetate; palladium diacetate; tris-(o-tolyl)phosphine in N,N-dimethyl-formamide T=130°C; Heck reaction; 16 h; Inert atmosphere;
参考文献
Applied Organometallic Chemistry, , vol. 25, # 4 p. 289 - 293
反应条件
1: S, aq. Na2S 2: NaNO2, aq. HBF4 3: (pyrolysis) 4: SnCl2, aq. HCl View Scheme
参考文献
Fletcher,T.L. et al.
Journal of Organic Chemistry, 1960 , vol. 25, p. 1342 - 1348
反应条件
1.1: 98 percent / SnCl2 / ethyl acetate / Heating 2.1: NaNO2; aq. H2SO4 / 0 °C 2.2: 68 percent / KI; H2O View Scheme
参考文献
Rodriguez, J. Gonzalo; Tejedor, J. Luis; Esquivias, Jorge; Diaz, Cristina
Tetrahedron Letters, 2003 , vol. 44, # 34 p. 6375 - 6378
反应条件
tin(ll) chloride in ethyl acetate
参考文献
Lux, Jacques; Chan, Minnie; Vander Elst, Luce; Schopf, Eric; Mahmoud, Enas; Laurent, Sophie; Almutairi, Adah
Journal of Materials Chemistry B, 2013 , vol. 1, # 46 p. 6359 - 6364
参考文献
Wolff, J. Jens; Gredel, Frank; Oeser, Thomas; Irngartinger, Hermann; Pritzkow, Hans
Chemistry--A European Journal, 1999 , vol. 5, # 1 p. 29 - 38
反应条件
1: vinyl-magnesium bromide With zinc(II) chloride in tetrahydrofuran
T=0 - 20°C; 1.16667 h;
2: 1-Iodo-3,5-dinitrobenzene With bis-triphenylphosphine-palladium(II) chloride; 2,6-di-tert-butyl-4-methyl-phenol in tetrahydrofuran
T=20°C; Negishi coupling; 18 h;
参考文献
Jian, Huahua; Tour, James M.
Journal of Organic Chemistry, 2005 , vol. 70, # 9 p. 3396 - 3424
反应条件
sodium acetate; palladium diacetate; tris-(o-tolyl)phosphine in N,N-dimethyl-formamide
T=90°C; Heck reaction; P=7600.51 Torr; 3 h; Inert atmosphereAutoclave;
参考文献
Nobre, Sabrina M.; Muniz, Mauro N.; Seferin, Marcus; Da Silva, Wagner M.; Monteiro, Adriano L.
Applied Organometallic Chemistry, 2011 , vol. 25, # 4 p. 289 - 293
反应条件
sodium acetate; palladium diacetate; tris-(o-tolyl)phosphine in N,N-dimethyl-formamide
T=90°C; Heck reaction; P=7600.51 Torr; 0.5 h; Inert atmosphereAutoclave;
参考文献
Nobre, Sabrina M.; Muniz, Mauro N.; Seferin, Marcus; Da Silva, Wagner M.; Monteiro, Adriano L.
Applied Organometallic Chemistry, 2011 , vol. 25, # 4 p. 289 - 293
反应条件
sodium acetate; palladium diacetate; tris-(o-tolyl)phosphine in N,N-dimethyl-formamide
Heck reaction; P=3800.26 Torr; Inert atmosphereAutoclave;
参考文献
Nobre, Sabrina M.; Muniz, Mauro N.; Seferin, Marcus; Da Silva, Wagner M.; Monteiro, Adriano L.
Applied Organometallic Chemistry, 2011 , vol. 25, # 4 p. 289 - 293
