反应条件
1: With [RuCl2(p-cumene)]2; trifuran-2-yl-phosphane; sodium carbonate in toluene T=50°C; Schlenk techniqueInert atmosphere; 2: With bis(norbornadiene)rhodium(I) tetrafluoroborate; C46H35NO2P2; hydrogen in tetrahydrofuran T=20°C; P=15001.5 Torr; 1 h; Schlenk techniqueInert atmosphereAutoclave; 3: With sodium hydroxide in methanol T=20°C; 2 h; Schlenk techniqueInert atmosphere; Overall yield = 68 percent; Overall yield = 145.4 mg; enantioselective reaction;
参考文献
Konrad, Tina Maria; Schmitz, Pascal; Leitner, Walter; Francio, Giancarlo
Chemistry - A European Journal, 2013 , vol. 19, # 40 p. 13299 - 13303
