1.1: n-butyllithium / tetrahydrofuran; hexane / 5 h / -78 °C 1.2: 0.75 h / -50 °C 2.1: potassium carbonate / N,N-dimethyl-formamide / 20 h / 20 °C 3.1: sodium hydride / tetrahydrofuran; mineral oil / 2 h / 20 °C / |Inert atmosphere 3.2: 12 h / 20 °C / |Inert atmosphere View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 53, # 14 p. 3722 - 3726
Angew. Chem., , vol. 126, # 14 p. 3796 - 3800,5
allyl nickel bromide dimer; (S)-(-)-2-methoxy-2'-diphenylphosphino-1,1'-binaphthyl; Na[B(3,5-(CF3)2C6H3)4] in dichloromethane T=0°C; Addition; P=760 Torr; 5.5 h; Title compound not separated from byproducts;
