hydrogenchloride; sodium hydroxide; CO; CuCl2; palladium dichloride in tetrahydrofuran; water; toluene

hydrogenchloride; water; palladium diacetate; di-(1-adamantyl)-n-butylphosphine in 1,4-dioxane T=100°C; P=30003 Torr; 20 h; regioselective reaction;

(10H)-phenothiazine; bis(.mu.-chloro)bis{(2-(1-(hydroxyimino)methyl)phenyl-C1,N)palladium(II)}; potassium acetate in N,N-dimethyl acetamide T=105°C; Heck-Mizoroki reaction; P=775.743 Torr; 18 h; Inert atmosphere;

1: (3-Bromo-phenyl)-phenyl-methanone With tetrakis(triphenylphosphine) palladium(0) in ethylene glycol dimethyl ether T=20°C; 0.333333 h; Inert atmosphere; 2: 2,4,6-trivinylcyclotriboroxane pyridine complex With potassium carbonate in ethylene glycol dimethyl ether; water Suzuki coupling; 20 h; Inert atmosphereReflux;

bis(tri-o-tolylphosphine)palladium acetate in methanol T=20°C; 0.166667 h;

1: m-Aminobenzophenone Diazotization; 2: potassium vinyl trifluoroborate With bis(tri-o-tolylphosphine)palladium acetate in methanol T=20°C; Arylation; 0.166667 h;

N,N,N',N,-tetramethylethylenediamine; palladium diacetate; di-(1-adamantyl)-n-butylphosphine in toluene T=80°C; Suzuki carbonylation; P=1875.19 Torr; 24 h; Inert atmosphere;

tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=65°C; 3 h;

1.1: AlCl3, aluminium chloride 2.1: tetrakis(triphenylphosphine) palladium(0) / ethylene glycol dimethyl ether / 0.33 h / 20 °C / Inert atmosphere 2.2: 20 h / Inert atmosphere; Reflux View Scheme

1.1: AlCl3, aluminium chloride 2.1: tetrakis(triphenylphosphine) palladium(0) / ethylene glycol dimethyl ether / 0.33 h / 20 °C / Inert atmosphere 2.2: 20 h / Inert atmosphere; Reflux View Scheme