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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-甲氧基苯乙烯
合成路线
(共 543 条)
637-69-4
4-甲氧基苯乙烯
+
108-94-1
环己酮
→
反应条件
54669-75-9
反应条件
1: cyclohexanone With pyrrolidinium hydrochloride in water; N,N-dimethyl-formamide T=70°C; 2: 4-methoxy-1-vinyl-benzene With manganese(IV) oxide; Cu(ClO4)2*6H2O in water; N,N-dimethyl-formamide T=70°C; 48 h;
参考文献
Xie, Jin; Huang, Zhi-Zhen
Chemical Communications, 2010 , vol. 46, # 11 p. 1947 - 1949
637-69-4
4-甲氧基苯乙烯
→
反应条件
55455-94-2
反应条件
1.1: nBuLi / tetrahydrofuran; hexane / 0.17 h / 20 °C 1.2: 99 percent / tetrahydrofuran; hexane / 24 h / 20 °C 2.1: 98 percent / H2; Et3N / Pd(OH)2/C / ethanol / 15 h / 40 °C / 7500.75 Torr View Scheme
参考文献
Kumar, Kamal; Michalik, Dirk; Castro, Ivette Garcia; Tillack, Annegret; Zapf, Alexander; Arlt, Michael; Heinrich, Timo; Boettcher, Henning; Beller, Matthias
Chemistry - A European Journal, 2004 , vol. 10, # 3 p. 746 - 757
637-69-4
4-甲氧基苯乙烯
→
反应条件
59115-41-2
+
53400-00-3
+
34221-26-6
反应条件
[MeCNAu((1,1′-biphenyl-2-yl)-di-tert-butylphosphine)]+SbF6− in dichloromethane T=23°C; 12 h; Inert atmosphere; optical yield given as percent de;
参考文献
Solorio-Alvarado, Cesar R.; Echavarren, Antonio M.
Journal of the American Chemical Society, 2010 , vol. 132, # 34 p. 11881 - 11883
637-69-4
4-甲氧基苯乙烯
→
反应条件
6052-84-2
反应条件
1: Grubb's 2nd generation catalyst / dichloromethane / 2 h / 40 °C 2: palladium on activated charcoal; hydrogen / tetrahydrofuran / 6 h / 20 °C 3: boron dimethyl-trifluoro sulphide / dichloromethane / 12 h / 20 °C View Scheme
参考文献
Yamaguchi, Yusuke; Okada, Yohei; Chiba, Kazuhiro
Journal of Organic Chemistry, 2013 , vol. 78, # 6 p. 2626 - 2638
637-69-4
4-甲氧基苯乙烯
+
108-98-5
→
反应条件
60702-13-8
反应条件
anhydrous iron chloride; AgNTf2 in 1,4-dioxane T=80°C; 24 h; regioselective reaction;
参考文献
Cabrero-Antonino, Jose R.; Leyva-Perez, Antonio; Corma, Avelino
Advanced Synthesis and Catalysis, 2012 , vol. 354, # 4 p. 678 - 687
637-69-4
4-甲氧基苯乙烯
+
523-27-3
→
反应条件
60949-09-9
反应条件
potassium phosphate; palladium diacetate in N,N-dimethyl acetamide T=110°C; 24 h;
参考文献
Wang, Fangfang; Wen, Jiying; Huang, Lingyun; Huang, Jinjiu; Jin, Ouyang
Chemical Communications, 2012 , vol. 48, # 59 p. 7395 - 7397
637-69-4
4-甲氧基苯乙烯
+
670-54-2
→
反应条件
61715-62-6
反应条件
in toluene 72 h; Heating;
参考文献
Aly, Ashraf A.; Mourad, Aboul-Fetouh E.
Tetrahedron, 1993 , vol. 49, # 33 p. 7325 - 7336
637-69-4
4-甲氧基苯乙烯
+
563-41-7
→
反应条件
6292-71-3
反应条件
sodium acetate in ethanol; water
参考文献
Kashaw, Sushil K.; Gupta, Vivek; Kashaw, Varsha; Mishra; Stables; Jain
Medicinal Chemistry Research, 2010 , vol. 19, # 3 p. 250 - 261
637-69-4
4-甲氧基苯乙烯
+
106-51-4
→
反应条件
63216-06-8
反应条件
trichloroacetic acid in toluene T=100°C;
参考文献
Manning, Wayne B.; Kelly, Terence P.; Muschik, Gary M.
Journal of Organic Chemistry, 1980 , vol. 45, # 12 p. 2535 - 2536
637-69-4
4-甲氧基苯乙烯
→
反应条件
63216-06-8
反应条件
in water T=20°C; Cycloaddition; Diels-Alder reaction; 48 h;
参考文献
Carreno, M. Carmen; Urbano, Antonio
Tetrahedron Letters, 2000 , vol. 41, # 21 p. 4117 - 4121
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