3,4,5-三甲氧基甲苯合成路线 （共 96 条）
反应条件
1: conc. H2SO4, amylnitrite / ethanol / 0.67 h / 0 °C 2: H2(18)O / cyclohexane / 1.5 h / Heating 3: K2CO3 / acetone / 2 h / Heating View Scheme
参考文献
Chemische Berichte, , vol. 114, # 5 p. 1963 - 1966
反应条件
1: LiAlH4 2: H2 / Pd-C 3: K2CO3 View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 15B, p. 18 - 20
反应条件
1: bromine / 1,2-dichloro-ethane / 7 h / 20 - 25 °C 2: sodium hydroxide / water; 1,2-dichloro-ethane / 5 h / 30 - 35 °C 3: copper(l) chloride / methanol; N,N-dimethyl-formamide / 8 h / 140 °C / |Autoclave View Scheme
参考文献
Organic Process Research and Development, , vol. 10, # 3 p. 487 - 492
反应条件
1: sodium hydroxide / water; 1,2-dichloro-ethane / 5 h / 30 - 35 °C 2: copper(l) chloride / methanol; N,N-dimethyl-formamide / 8 h / 140 °C / |Autoclave View Scheme
参考文献
Organic Process Research and Development, , vol. 10, # 3 p. 487 - 492
反应条件
potassium carbonate in acetone 2 h; Heating; Yield given;
参考文献
Chemische Berichte, , vol. 114, # 5 p. 1963 - 1966
反应条件
methanol-d4; palladium dichloride T=40°C; Green chemistry; chemoselective reaction;
参考文献
Advanced Synthesis and Catalysis, , vol. 355, # 2-3 p. 341 - 347
反应条件
in methanol Irradiation;
参考文献
Journal of Organic Chemistry, , vol. 59, # 19 p. 5587 - 5595
反应条件
1: pyridine / diethyl ether / 2 h / |Reflux; |Inert atmosphere 2: N,N,N',N'-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a;2',1'-c][1,4] diazepine-2,12-diamine / N,N-dimethyl-formamide / 24 h / |Inert atmosphere; |Glovebox; |UV-irradiation View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 8 p. 2239 - 2242
Angew. Chem., , vol. 125, # 8 p. 2295 - 2298,4
反应条件
1.1: sodium hydride / tetrahydrofuran / 0.5 h / 0 - 20 °C / |Inert atmosphere 1.2: 16 h / |Inert atmosphere; |Reflux 2.1: N,N,N',N'-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a;2',1'-c][1,4] diazepine-2,12-diamine / N,N-dimethyl-formamide / 72 h / |Inert atmosphere; |Glovebox; |UV-irradiation View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 8 p. 2239 - 2242
Angew. Chem., , vol. 125, # 8 p. 2295 - 2298,4
反应条件
Aspergillus glaucus MA0196 in ethanol T=25°C; other reagents; Product distribution;
参考文献
Bioscience, Biotechnology, and Biochemistry, , vol. 61, # 8 p. 1386 - 1387
