1: n-butyllithium With anhydrous iron chloride in hexanes T=-78°C; 3 h; Inert atmosphere; 2: diphenyl acetylene in hexanes T=-78 - 25°C; Inert atmosphere; 3: With hydrogenchloride; water in hexanes
参考文献
European Journal of Organic Chemistry, , # 15 p. 2971 - 2977
Pd(PhP(t-Bu)2)2; sodium t-butanolate in ethanol; water T=80°C; Suzuki-Miyaura coupling; 24 h; Inert atmosphere; optical yield given as percent destereoselective reaction;
参考文献
Lu, Guo-Ping; Voigtritter, Karl R.; Cai, Chun; Lipshutz, Bruce H.
Journal of Organic Chemistry, 2012 , vol. 77, # 8 p. 3700 - 3703
mono(bis(di-tert-butyl(4-(dimethylamino)phenyl)phosphonio)palladium(II))dichloride; potassium carbonate in tetrahydrofuran; water T=20°C; Suzuki-Miyaura coupling; 5 h; Inert atmosphere; optical yield given as percent destereoselective reaction;
参考文献
Journal of Organic Chemistry, , vol. 77, # 8 p. 3700 - 3703
