(R)-(-)-4-烯基-2-戊醇合成路线 （共 30 条）
反应条件
Yield given. Multistep reaction;
参考文献
Journal of Organic Chemistry, , vol. 51, # 4 p. 432 - 439
反应条件
(i) (+)-2-exo,-3-exo-dihydroxy-3-endo-phenyl-bornane, THF, (ii) /BRN= 505984/, n-hexane, (iii) (HOCH2CH2)3N; Multistep reaction;
参考文献
Angewandte Chemie, , vol. 90, p. 822 - 823
反应条件
sodium hydroxide; dihydrogen peroxide entantioselectivity, other allyldialkylboranes; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 49, # 21 p. 4089 - 4091
参考文献
Levene; Haller
Journal of Biological Chemistry, 1929 , vol. 81, p. 427
Science (Washington, DC, United States), vol. 69, p. 47
Chem. Zentralbl., 1929 , vol. 100, # I p. 1211
反应条件
hydrogen; platinum on activated charcoal
参考文献
Brown, Herbert C.; Jadhav, Prabhakar K.
Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 4089 - 4091
反应条件
sodium dichromate; dimethylsulfide borane complex; sulfuric acid 1.) Et2O, a) -78 to 25 deg C, b) 25 deg C, 12 h, 2.) reflux, 1 h; Yield given. Multistep reaction;
参考文献
Brown; Kulkarni; Racherla
Journal of Organic Chemistry, 1994 , vol. 59, # 2 p. 365 - 369
反应条件
1: 77.1 percent / Et3N, DMAP / CH2Cl2 / 17 h / 25 °C 2: 1) 9-BBN, 2) NaOH, H2O2 / 1) THF, 25 deg C, 19h, 2a) 0 deg C, 30 min, 2b) 25 deg C, 10h 3: 95 percent / CBr4, PPh3, K2CO3 / CH2Cl2 / 0.5 h / 0 °C 5: 80 percent / 5percent HCl / tetrahydrofuran / 216 h / 25 °C View Scheme
参考文献
Journal of Organic Chemistry, , vol. 56, # 8 p. 2883 - 2894
反应条件
Beim Ozonisieren, Eintragen des Ozonids in Wasser und Kochen der Loesung mit Silberoxyd;
参考文献
Levene; Haller
Journal of Biological Chemistry, 1929 , vol. 81, p. 427
Science (Washington, DC, United States), vol. 69, p. 47
Chem. Zentralbl., 1929 , vol. 100, # I p. 1211
反应条件
Beim Ozonisieren, Eintragen des Ozonids in Wasser und Kochen der Loesung mit Silberoxyd;
参考文献
Levene; Haller
Journal of Biological Chemistry, 1929 , vol. 81, p. 427
Science (Washington, DC, United States), vol. 69, p. 47
Chem. Zentralbl., 1929 , vol. 100, # I p. 1211
反应条件
sodium hydroxide; n-butyllithium; dimethylsulfide borane complex; dihydrogen peroxide
Multistep reaction;
参考文献
Nguyen; Sherman; Ball; Solow; Singaram
Tetrahedron Asymmetry, 1993 , vol. 4, # 2 p. 189 - 192
