2,2’-(1,6-己二基二氧代)二苯(甲)醛合成路线 （共 6 条）
反应条件
potassium hydroxide; Aliquatreg; 336
参考文献
Meier, Herbert; Schwertel, Manfred; Kolshorn, Heinz
Helvetica Chimica Acta, 2013 , vol. 96, # 11 p. 2009 - 2019
反应条件
1: 1,6-bis(2-iodophenoxy)hexane With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in tetrahydrofuran; hexane
T=0 - 20°C; Inert atmosphere;
2: N,N-dimethyl-formamide in tetrahydrofuran; hexane
T=20°C; 1 h; Inert atmosphere;
参考文献
Bedard, Anne-Catherine; Collins, Shawn K.
Journal of the American Chemical Society, 2011 , vol. 133, # 49 p. 19976 - 19981
反应条件
potassium carbonate in acetonitrile
8 h; Reflux;
参考文献
Pei, Dong; Zhang, Yu; Wei, Siyu; Wang, Meng; Sun, Jian
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 4 p. 619 - 623
反应条件
sodium hydroxide in ethanol
Alkylation; 72 h; Heating;
参考文献
Simion, Cristian; Simion, Alina; Mitoma, Yoshiharu; Nagashima, Satoko; Kawaji, Takatoshi; Hashimoto, Iwao; Tashiro, Masashi
Heterocycles, 2000 , vol. 53, # 11 p. 2459 - 2470
反应条件
1.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 15 h / Inert atmosphere; Reflux
2.1: n-butyllithium; N,N,N',N,-tetramethylethylenediamine / tetrahydrofuran; hexane / 0 - 20 °C / Inert atmosphere
2.2: 1 h / 20 °C / Inert atmosphere
View Scheme
参考文献
Bedard, Anne-Catherine; Collins, Shawn K.
Journal of the American Chemical Society, 2011 , vol. 133, # 49 p. 19976 - 19981
反应条件
1.1: di-isopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 15 h / Inert atmosphere; Reflux
2.1: n-butyllithium; N,N,N',N,-tetramethylethylenediamine / tetrahydrofuran; hexane / 0 - 20 °C / Inert atmosphere
2.2: 1 h / 20 °C / Inert atmosphere
View Scheme
参考文献
Bedard, Anne-Catherine; Collins, Shawn K.
Journal of the American Chemical Society, 2011 , vol. 133, # 49 p. 19976 - 19981
