in dichloromethane-d2 under Ar; a soln. of Ru-contg. compd. (0.06 mmol) in CD2Cl2 was treated with P(i)Pr3 (0.06 mmol); a quick change of colour from yellow to red; detd. by (1)H and (31)P NMR spectra;
参考文献
Jung, Stefan; Brandt, Carsten D.; Wolf, Justin; Werner, Helmut
Dalton Transactions, 2004 , # 3 p. 375 - 383
in dichloromethane-d2 under Ar; a soln. of Ru-contg. compd. (0.06 mmol) in CD2Cl2 was treated with P(i)Pr3 (0.06 mmol); a quick change of colour from yellow to red; detd. by (1)H and (31)P NMR spectra;
参考文献
Jung, Stefan; Brandt, Carsten D.; Wolf, Justin; Werner, Helmut
Dalton Transactions, 2004 , # 3 p. 375 - 383
in ethanol byproducts: COD; 1 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; evapn., extn. (benzene), recrystn. (benzene/hexane);
in toluene
Irradiation (UV/VIS); sample sealed under vac. in silica tubes, photolyzed with light from 500 W high pressure Hg arc at -80 to -6°C; not isolated; detected by ESR;
参考文献
Brindley, Peter B.; Davies, Alwyn G.; Hawari, Jalal A.-A.
Journal of Organometallic Chemistry, 1983 , vol. 250, # 1 p. 247 - 256
Abdur-Rashid, Kamaluddin; Fong, Tina P.; Greaves, Bronwyn; Gusev, Dmitry G.; Hinman, Justin G.; Landau, Shaun E.; Lough, Alan J.; Morris, Robert H.
Journal of the American Chemical Society, 2000 , vol. 122, # 38 p. 9155 - 9171
sodium naphthalenide in tetrahydrofuran
byproducts: NaCl; (Ar, Schlenk) a soln. of sodium naphthalenide in THF was added dropwise to the suspn. of Pt-complex and phosphine in THF, stirred for 2 h; the solvent was removed under vac., an excess of naphthalene was sublimed, the residue was extd. with hexane, filtered;
参考文献
Nova, Ainara; Erhardt, Stefan; Jasim, Naseralla A.; Perutz, Robin N.; Macgregor, Stuart A.; McGrady, John E.; Whitwood, Adrian C.
Journal of the American Chemical Society, 2008 , vol. 130, # 46 p. 15499 - 15511
