3-环己烯-1-羧酸甲酯合成路线 （共 53 条）
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in N,N-dimethyl-formamide T=20 - 120°C; 18 h;
参考文献
EP2368870 A1, ;
Page/Page column 13 ;
EP 2368870 A1
反应条件
1: 82 percent / sodium methoxide / 10 h / Ambient temperature 2: 77 percent / perchloric acid / ethyl acetate; H2O / 2 h / Ambient temperature 3: 70 percent / sodium methoxide / methanol / 7.5 h / Ambient temperature 4: 40 percent / sodium methoxide / benzene / 3 h / Heating 5: pyridine / 9 h / Ambient temperature 6: trimethylammonium acetate / tetrakis(triphenylphosphine)palladium(0) / tetrahydrofuran / 3.5 h / Heating View Scheme
参考文献
Journal of the American Chemical Society, , vol. 102, p. 4730
反应条件
1: 40 percent / sodium methoxide / benzene / 3 h / Heating 2: pyridine / 9 h / Ambient temperature 3: trimethylammonium acetate / tetrakis(triphenylphosphine)palladium(0) / tetrahydrofuran / 3.5 h / Heating View Scheme
参考文献
Journal of the American Chemical Society, , vol. 102, p. 4730
反应条件
1: 77 percent / perchloric acid / ethyl acetate; H2O / 2 h / Ambient temperature 2: 70 percent / sodium methoxide / methanol / 7.5 h / Ambient temperature 3: 40 percent / sodium methoxide / benzene / 3 h / Heating 4: pyridine / 9 h / Ambient temperature 5: trimethylammonium acetate / tetrakis(triphenylphosphine)palladium(0) / tetrahydrofuran / 3.5 h / Heating View Scheme
参考文献
Journal of the American Chemical Society, , vol. 102, p. 4730
反应条件
1: 70 percent / sodium methoxide / methanol / 7.5 h / Ambient temperature 2: 40 percent / sodium methoxide / benzene / 3 h / Heating 3: pyridine / 9 h / Ambient temperature 4: trimethylammonium acetate / tetrakis(triphenylphosphine)palladium(0) / tetrahydrofuran / 3.5 h / Heating View Scheme
参考文献
Journal of the American Chemical Society, , vol. 102, p. 4730
反应条件
hydroquinone in toluene T=110°C; Diels-Alder reaction; 48 h; Inert atmosphere;
参考文献
Organic and Biomolecular Chemistry, , vol. 10, # 22 p. 4407 - 4416
反应条件
dipyridinium dichromate in N,N-dimethyl-formamide Ambient temperature;
参考文献
O'Connor, Brian; Just, George
Tetrahedron Letters, 1987 , vol. 28, # 28 p. 3235 - 3236
反应条件
trimethylammonium acetate; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran 3.5 h; Heating;
参考文献
Journal of the American Chemical Society, , vol. 102, p. 4730
反应条件
tetrafluoroboric acid diethyl ether complex; tributylphosphine; tris(dibenzylideneacetone)dipalladium (0) T=80°C; 5 h;
参考文献
Chemical Communications, , # 17 p. 2132 - 2133
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in 1,4-dioxane 1 h; Heating;
参考文献
Hirsch, Jerry A.; Truc, Vu Chi
Journal of Organic Chemistry, 1986 , vol. 51, # 12 p. 2218 - 2227
