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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
3-癸基噻吩
合成路线
（共 6 条）
872-31-1
3-溴噻吩
+
2050-77-3
1-碘癸烷
→
反应条件
65016-55-9
3-癸基噻吩
反应条件
N,N,N',N,-tetramethylethylenediamine; PdCl2(amphos)2; zinc in water T=20°C; Negishi-like cross-coupling; 24 h; Inert atmosphere;
参考文献
Krasovskiy, Arkady; Thome, Isabelle; Graff, Julien; Krasovskaya, Valeria; Konopelski, Paul; Duplais, Christophe; Lipshutz, Bruce H.
Tetrahedron Letters, 2011 , vol. 52, # 17 p. 2203 - 2205
872-31-1
3-溴噻吩
+
17049-50-2
癸基溴化镁
→
反应条件
65016-55-9
3-癸基噻吩
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether T=20 - 60°C; Inert atmosphere;
参考文献
Guo, Xugang; Ortiz, Rocio Ponce; Zheng, Yan; Hu, Yan; Noh, Yong-Young; Baeg, Kang-Jun; Facchetti, Antonio; Marks, Tobin J.
Journal of the American Chemical Society, 2011 , vol. 133, # 5 p. 1405 - 1418
872-31-1
3-溴噻吩
+
112-29-8
癸基溴
→
反应条件
65016-55-9
3-癸基噻吩
反应条件
1: 1-bromo-decane With magnesium in diethyl ether Reflux; 2: thien-3-yl bromide With [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in diethyl ether T=0°C; RefluxInert atmosphere;
参考文献
Wang, Bao; Tsang, Sai-Wing; Zhang, Weifeng; Tao, Ye; Wong, Man Shing
Chemical Communications, 2011 , vol. 47, # 33 p. 9471 - 9473
872-31-1
3-溴噻吩
→
反应条件
3172-56-3
3,3'-双噻吩
+
65016-55-9
3-癸基噻吩
反应条件
1: 1-bromo-decane With magnesium; [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in 2-methyl tetrahydrofuran T=20°C; 2.5 h; 2: thien-3-yl bromide in 2-methyl tetrahydrofuran T=20°C; Kumada Coupling Reaction; Product distribution / selectivity;
参考文献
US2006/155134 A1, ;
Page/Page column 3 ;
872-31-1
3-溴噻吩
+
112-29-8
癸基溴
→
反应条件
3172-56-3
3,3'-双噻吩
+
740804-46-0
+
65016-55-9
3-癸基噻吩
反应条件
1: thien-3-yl bromide; 1-bromo-decane With magnesium; [1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran T=20°C; 48 h; 2: thien-3-yl bromide in 2-methyl tetrahydrofuran T=20°C; Kumada Coupling Reaction; Product distribution / selectivity;
参考文献
US2006/155134 A1, ;
Page/Page column 5 ;
65016-55-9
3-癸基噻吩
→
反应条件
158956-23-1
2,5-二溴-3-癸基噻吩
反应条件
bromine in chloroform Ambient temperature;
参考文献
Guoshun, Yang; Keda, Hu; Yang, Qin
Journal of Polymer Science, Part A: Polymer Chemistry, 2014 , vol. 52, # 5 p. 591 - 595
