1,1-双(三甲基甲硅烷基氧基)-2-三甲基甲硅烷基乙烯合成路线 （共 32 条）
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran 4 h; Ambient temperature;
参考文献
Bellasoued, Moncef; Gaudemar, Marcel
Tetrahedron Letters, 1988 , vol. 29, # 36 p. 4551 - 4554
反应条件
1: With titanium tetrachloride in dichloromethane T=-78 - 25°C; 2: With ammonium chloride in dichloromethane; water T=-78°C; Further stages.;
参考文献
Bellassoued; Mouelhi; Lensen
Journal of Organic Chemistry, 2001 , vol. 66, # 15 p. 5054 - 5057
反应条件
lithium diisopropyl amide in tetrahydrofuran
T=-80°C; 0.5 h;
参考文献
Lensen; Mouelhi; Bellassoued
Synthetic Communications, 2001 , vol. 31, # 7 p. 1007 - 1011
反应条件
triethylamine in diethyl ether
0.7 h; Ambient temperature; Yields of byproduct given;
参考文献
Emde, Herbert; Simchen, Gerhard
Liebigs Annalen der Chemie, 1983 , # 5 p. 816 - 834
反应条件
1: 82 percent / LDA / diethyl ether; tetrahydrofuran / 1.) -70 deg C, overnight, 2.) -70 deg C to room temperature
2: 91 percent / LDA / tetrahydrofuran / 0.5 h / -80 °C
View Scheme
参考文献
Bellassoued, Moncef; Lensen, Nathalie; Bakasse, Mina; Mouelhi, Sinda
Journal of Organic Chemistry, 1998 , vol. 63, # 24 p. 8785 - 8789
反应条件
triethylamine in diethyl ether
参考文献
Emde,H.; Simchen,G.
Synthesis, 1977 , p. 867 - 869
反应条件
1: With titanium tetrachloride in dichloromethane
T=-78 - 25°C;
2: With ammonium chloride in dichloromethane; water
T=-78°C; Further stages.;
参考文献
Bellassoued; Mouelhi; Lensen
Journal of Organic Chemistry, 2001 , vol. 66, # 15 p. 5054 - 5057
反应条件
1: With cesium fluoride
T=-30°C; 0.5 h;
2: With water
T=-30°C; Further stages.;
参考文献
Bellassoued; Mouelhi; Lensen
Journal of Organic Chemistry, 2001 , vol. 66, # 15 p. 5054 - 5057
反应条件
titanium chloride in dichloromethane
T=-70 - 20°C; 4 h;
参考文献
Bellassoued, Moncef; Mouelhi, Sinda; Fromentin, Pierre; Gonzalez, Aurelien
Journal of Organometallic Chemistry, 2005 , vol. 690, # 9 p. 2172 - 2179
反应条件
1: With potassium hydroxide in N,N-dimethyl-formamide
T=20°C; 5 h;
2: With ammonium chloride in water
参考文献
Lensen; Mouelhi; Bellassoued
Synthetic Communications, 2001 , vol. 31, # 7 p. 1007 - 1011
