1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
TASF-(Et) in tetrahydrofuran
T=-30°C; 3 h;
参考文献
Noyori, R.; Nishida, I.; Sakata, J.
Journal of the American Chemical Society, 1983 , vol. 105, # 6 p. 1598 - 1608
反应条件
molecular sieve; BnNMe3(+)F(-) in tetrahydrofuran
1.) room temperature, overnight, 2.) 0 deg C, 10 min, 3.) room temperature, ,24 h;
参考文献
Kuwajima, Isao; Nakamura, Eiichi; Shimizu, Makoto
Journal of the American Chemical Society, 1982 , vol. 104, # 4 p. 1025 - 1030
反应条件
1: 83 percent / TiCl4 / CH2Cl2 / 1 h / -23 °C
2: 90 percent / W-2 Raney nickel / acetone; ethanol / 2 h / 20 °C
View Scheme
参考文献
Paterson, Ian
Tetrahedron, 1988 , vol. 44, # 13 p. 4207 - 4220
反应条件
zinc(II) chloride in ethyl acetate
T=60 - 70°C; 0.3 h;
参考文献
Amerkhanov, R. R.; Gal'chenko, E. P.; Musavirov, R. S.; Rakhmankulov, D. L.
Russian Journal of General Chemistry, 1993 , vol. 63, # 3.2 p. 468 - 470
Zhurnal Obshchei Khimii, 1993 , vol. 63, # 3 p. 663 - 667
反应条件
zinc(II) chloride in ethyl acetate
T=60 - 70°C; 5 h;
参考文献
Amerkhanov, R. R.; Gal'chenko, E. P.; Musavirov, R. S.; Rakhmankulov, D. L.
Russian Journal of General Chemistry, 1993 , vol. 63, # 3.2 p. 468 - 470
Zhurnal Obshchei Khimii, 1993 , vol. 63, # 3 p. 663 - 667
反应条件
hydrogenchloride; zinc(II) chloride
1.) ethyl acetate, room temp., 18 h; 2.) 65-70 deg C, 30 min; Yield given. Multistep reaction;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
zinc(II) chloride in ethyl acetate
18 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
2,6-dichloro-benzonitrile
1) ethylene oxide / -15 deg C / photolysis 2) EtOH / 23 deg C; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Block, Eric; Aslam, Mohammad; Iyer, Rajeshwari; Hutchinson, John
Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3664 - 3666
反应条件
gallium(III) chloride; sulfuric acid
1.) methylcyclohexane, RT, 2.) methylcyclohexane, THF; Yield givenMultistep reaction. Yields of byproduct given;
参考文献
Yamaguchi, Masahiko; Tsukagoshi, Toru; Arisawa, Mieko
Journal of the American Chemical Society, 1999 , vol. 121, # 16 p. 4074 - 4075
反应条件
lithium perchlorate in diethyl ether
Ambient temperature;
参考文献
Saraswathy, V. Geetha; Sankararaman, S.
Journal of Organic Chemistry, 1995 , vol. 60, # 16 p. 5024 - 5028
