1-(三甲基硅氧烷)环己烯合成路线 （共 370 条）
反应条件
hydrogen; [RuCl(η2-H2)(dppe)2]OTf in 1,2-dichloro-ethane
T=50°C; P=760 Torr; 48 h; Product distribution; Further Variations:Catalysts;
参考文献
Takei, Izuru; Nishibayashi, Yoshiaki; Ishii, Youichi; Mizobe, Yasushi; Uemura, Sakae; Hidai, Masanobu
Journal of Organometallic Chemistry, 2003 , vol. 679, # 1 p. 32 - 42
反应条件
in tetrahydrofuran
-70 deg C to r.t.; Yield given;
参考文献
Chen, Kuanchiang; Koser, Gerald F.
Journal of Organic Chemistry, 1991 , vol. 56, # 20 p. 5764 - 5767
反应条件
tetrakis(triphenylphosphine) palladium(0); n-butyllithium
1.) THF, hexane, -78 deg C, 2.) THF, hexane, a) -78 deg C, 1 h, b) RT, overnight; Yield given. Multistep reaction;
参考文献
Hirao, Toshikazu; Yamada, Naoto; Ohshiro, Yoshiki; Agawa, Toshio
Journal of Organometallic Chemistry, 1982 , vol. 236, # 3 p. 409 - 414
反应条件
trimethylsilyl trifluoromethanesulfonate in dichloromethane
4 h; Ambient temperature;
参考文献
Hosomi, Akira; Sakata, Yasuyuki; Sakurai, Hideki
Chemistry Letters, 1983 , p. 405 - 408
反应条件
titanium tetrachloride in dichloromethane
参考文献
Mukaiyama,T. et al.
Journal of the American Chemical Society, 1974 , vol. 96, p. 7503 - 7509
反应条件
hydrogenchloride; zinc(II) chloride
1.) ethyl acetate, room temp.; Yield given. Multistep reaction;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
1: With zinc(II) chloride in ethyl acetate
2: With hydrogenchloride; water
参考文献
Kananovich, Dzmitry G.; Zubrytski, Dzmitry M.; Kulinkovich, Oleg G.
Synlett, 2010 , # 7 p. 1043 - 1046
反应条件
zinc(II) chloride in ethyl acetate
Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Makin, S. M.; Kruglikova, R. I.; Tagirov, T. K.; Kharitonova, O. V.
Journal of Organic Chemistry USSR (English Translation), 1984 , vol. 20, # 6 p. 1075 - 1078
Zhurnal Organicheskoi Khimii, 1984 , vol. 20, # 6 p. 1182 - 1185
反应条件
triethylsilyl trifluoromethanesulphonate in various solvent(s)
T=0°C; 1 h;
参考文献
Momiyama, Norie; Yamamoto, Hisashi
Angewandte Chemie - International Edition, 2002 , vol. 41, # 16 p. 2986 - 2988
反应条件
(S)-difluoroPhos; AgOTf; cesium fluoride in tetrahydrofuran; methanol
T=-78°C; optical yield given as percent ee;
参考文献
Kawasaki, Masanori; Li, Pingfan; Yamamoto, Hisashi
Angewandte Chemie - International Edition, 2008 , vol. 47, # 20 p. 3795 - 3797
