2-甲基-1-苯基-1,3-丁二酮合成路线 （共 34 条）
反应条件
1: With BF3*AcOH; toluene-4-sulfonic acid T=20°C; 12 h; 2: With sodium acetate in water 3 h; Heating;
参考文献
Matsukawa, Yohei; Isobe, Minoru; Kotsuki, Hiyoshizo; Ichikawa, Yoshiyasu
Journal of Organic Chemistry, 2005 , vol. 70, # 13 p. 5339 - 5341
反应条件
Wilkinson's catalyst; diethylzinc in tetrahydrofuran; hexane T=0 - 20°C; 24 h;
参考文献
Sato, Kazuyuki; Yamazoe, Satoshi; Yamamoto, Rie; Ohata, Shizuka; Tarui, Atsushi; Omote, Masaaki; Kumadaki, Itsumaro; Ando, Akira
Organic Letters, 2008 , vol. 10, # 12 p. 2405 - 2408
反应条件
1: benzoic acid With thionyl chloride; N,N-dimethyl-formamide in dichloromethane T=20°C; 20 h; 2: methyl vinyl ketone With Wilkinson's catalyst; diethylzinc in tetrahydrofuran; hexane T=0°C; 1 h;
参考文献
Sato, Kazuyuki; Yamazoe, Satoshi; Yamamoto, Rie; Ohata, Shizuka; Tarui, Atsushi; Omote, Masaaki; Kumadaki, Itsumaro; Ando, Akira
Organic Letters, 2008 , vol. 10, # 12 p. 2405 - 2408
反应条件
potassium carbonate in acetone 4 h; Inert atmosphereReflux;
参考文献
Bertogg, Andreas; Hintermann, Lukas; Huber, Dominique P.; Perseghini, Mauro; Sanna, Maria; Togni, Antonio
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 353 - 403
反应条件
hydrogen; palladium on activated charcoal in ethyl acetate
参考文献
Journal of the American Chemical Society, , vol. 94, p. 5086 - 5087
反应条件
4-methylpyridine 1-oxide; (IPr)AuCl; bis-(trifluoromethylsulphonyl)amine; AgNTf2 in dichloromethane T=20°C; 20 h;
参考文献
Hashmi, A. Stephen K.; Wang, Tao; Shi, Shuai; Rudolph, Matthias
Journal of Organic Chemistry, 2012 , vol. 77, # 17 p. 7761 - 7767
反应条件
tetrabutyl ammonium fluoride T=-78 - 25°C; 2 h;
参考文献
Barinelli, Lucio S.; Nicholas, Kenneth M.
Journal of Organic Chemistry, 1988 , vol. 53, # 9 p. 2114 - 2117
反应条件
in chloroform T=110 - 115°C; 48 h;
参考文献
Tetrahedron, , vol. 47, # 37 p. 8031 - 8042
反应条件
chloro-trimethyl-silane; water; sodium iodide in hexane 31 h; Ambient temperature;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 60, # 3 p. 1063 - 1066
反应条件
1: triethylamine, sodium iodide / acetonitrile 2: 93 percent Chromat. / bismuth(III) chloride, sodium iodide / CH2Cl2; diethyl ether / 0.67 h / Ambient temperature View Scheme
参考文献
Journal of Organic Chemistry, , vol. 61, # 11 p. 3885 - 3887
