3,4-环氧-1-环己烯合成路线 （共 12 条）
反应条件
hydrogen; montmorillonite-(OSi(OMe)2CH2CH2PPh2lt;Rugt;)x in benzene T=75°C; P=25857.4 Torr; 48 h;
参考文献
Journal of Organometallic Chemistry, , vol. 551, # 1-2 p. 349 - 354
反应条件
hydrogen; montmorillonite-(OSi(OMe)2CH2CH2PPh2lt;Rugt;)x in benzene T=75°C; P=25857.4 Torr; 48 h;
参考文献
Aldea, Raluca; Alper, Howard
Journal of Organometallic Chemistry, 1998 , vol. 551, # 1-2 p. 349 - 354
反应条件
sodium perchlorate; water in 1,4-dioxane T=25°C; pH 9.0;
参考文献
Ross, Angela M.; Pohl, Terese M.; Piazza, Kathryn; Thomas, Michael; Fox, Bonnie; Whalen, Dale L.
Journal of the American Chemical Society, 1982 , vol. 104, # 6 p. 1658 - 1665
反应条件
sodium perchlorate; water in 1,4-dioxane T=25°C; pH 7.0, pH - rate profile; Rate constantMechanism;
参考文献
Ross, Angela M.; Pohl, Terese M.; Piazza, Kathryn; Thomas, Michael; Fox, Bonnie; Whalen, Dale L.
Journal of the American Chemical Society, 1982 , vol. 104, # 6 p. 1658 - 1665
反应条件
1: 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; copper(l) chloride; sodium t-butanolate / tetrahydrofuran / 3 h / -20 °C / Inert atmosphere 2: dihydrogen peroxide; potassium hydrogencarbonate / tetrahydrofuran; ethanol; water / 2 h / 0 °C / Inert atmosphere View Scheme
参考文献
Sanz, Xavier; Lee, Graham M.; Pubill-Ulldemolins, Cristina; Bonet, Amadeu; Gulyas, Henrik; Westcott, Stephen A.; Bo, Carles; Fernandez, Elena
Organic and Biomolecular Chemistry, 2013 , vol. 11, # 40 p. 7004 - 7010
反应条件
palladium diacetate; triethylamine; triphenylphosphine in toluene
T=70°C;
参考文献
Rigby, James H; Bazin, Berangere; Meyer, J Hoyt; Mohammadi, Farahnaz
Organic letters, 2002 , vol. 4, # 5 p. 799 - 801
反应条件
lithium aluminium tetrahydride
参考文献
Scagnolari, Francesco; Modelli, Alberto; Bottoni, Andrea; Jones, Derek; Lazzari, Dario
Journal of the Chemical Society - Faraday Transactions, 1996 , vol. 92, # 9 p. 1447 - 1453
反应条件
1: CuCN / tetrahydrofuran
2: CrO3*2Py / CH2Cl2
View Scheme
参考文献
Laycock, Bronwyn; Kitching, William; Wickham, Geoffrey
Tetrahedron Letters, 1983 , vol. 24, # 51 p. 5785 - 5788
反应条件
(2-Th)Cu(Bu)(CN)Li2
1.) THF, room temperature, 1 h, 2.) -78 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tucci, Fabio C.; Chieffi, Andre; Comasseto, Joao V.; Marino, Joseph P.
Journal of Organic Chemistry, 1996 , vol. 61, # 15 p. 4975 - 4989
反应条件
(2-Th)Cu(Bu)(CN)Li2
1.) THF, room temperature, 1 h, 2.) room temperature, 2 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Tucci, Fabio C.; Chieffi, Andre; Comasseto, Joao V.; Marino, Joseph P.
Journal of Organic Chemistry, 1996 , vol. 61, # 15 p. 4975 - 4989
