1,2-o-二十六基-sn-甘油合成路线 （共 5 条）
反应条件
hydrogen; palladium on activated charcoal in tetrahydrofuran; methanol
Hydrogenolysis; 16 h;
参考文献
Gege, Christian; Vogel, Jan; Bendas, Gerd; Rothe, Ulrich; Schmidt, Richard R.
Chemistry - A European Journal, 2000 , vol. 6, # 1 p. 111 - 122
反应条件
tetra(n-butyl)ammonium hydroxide in tetrahydrofuran
Heating;
参考文献
Thompson, David H.; Svendsen, Chris B.; Meglio, Ciro Di; Anderson, Valerie C.
Journal of Organic Chemistry, 1994 , vol. 59, # 11 p. 2945 - 2955
反应条件
1: 68 percent / NaH; tetrabutylammonium iodide / dimethylformamide / 36 h / 20 °C
2: 87 percent / H2 / 10 percent Pd/C / tetrahydrofuran; methanol / 16 h
View Scheme
参考文献
Gege, Christian; Vogel, Jan; Bendas, Gerd; Rothe, Ulrich; Schmidt, Richard R.
Chemistry - A European Journal, 2000 , vol. 6, # 1 p. 111 - 122
反应条件
1: 82 percent / CF3SO3H / CHCl3 / 24 h / 60 - 65 °C
2: 89 percent / Proton Sponge / CH2Cl2 / 48 h / Heating
3: 67 percent / 40percent aq. tetrabutylammonium hydroxide / tetrahydrofuran / Heating
View Scheme
参考文献
Thompson, David H.; Svendsen, Chris B.; Meglio, Ciro Di; Anderson, Valerie C.
Journal of Organic Chemistry, 1994 , vol. 59, # 11 p. 2945 - 2955
反应条件
1: 89 percent / Proton Sponge / CH2Cl2 / 48 h / Heating
2: 67 percent / 40percent aq. tetrabutylammonium hydroxide / tetrahydrofuran / Heating
View Scheme
参考文献
Thompson, David H.; Svendsen, Chris B.; Meglio, Ciro Di; Anderson, Valerie C.
Journal of Organic Chemistry, 1994 , vol. 59, # 11 p. 2945 - 2955
