(1-氨基-1-环己基)磷酸合成路线 （共 9 条）
反应条件
hydrogenchloride; water T=120°C; 3 h; Sealed tube;
参考文献
Moreno Pineda, Eufemio; Tuna, Floriana; Pritchard, Robin G.; Regan, Andrew C.; Winpenny, Richard E.P.; McInnes, Eric J. L.
Chemical Communications, 2013 , vol. 49, # 34 p. 3522 - 3524
反应条件
1: 1.) BuLi / 1.) THF, -78 deg C, 30 min, 2.) THF, -78 deg C, 1 h 2: tetrahydrofuran; acetic acid / 3 h / Ambient temperature 3: 77 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 4: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: 1.) BuLi / 1.) THF, -78 deg C, 30 min, 2.) THF, -78 deg C, 1 h 2: tetrahydrofuran; acetic acid / 3 h / Ambient temperature 3: 64 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 4: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: 77 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 2: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: 64 percent / H2 / Pd/C / ethanol / 3 h / 20 °C / 750.06 Torr 2: aq. HCl / 7 h / Heating View Scheme
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
1: acetamide With acetyl chloride in acetic acid 0.25 h; Cooling with ice; 2: ethyl 2-oxo-cyclohexanecarboxylate in acetic acid T=20°C; Cooling with ice; Further stages;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 184, # 4 p. 1047 - 1053
反应条件
hydrogenchloride 7 h; Heating;
参考文献
Synthetic Communications, , vol. 26, # 22 p. 4131 - 4143
反应条件
hydrogenchloride; water
参考文献
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 314,321; engl. Ausg. S. 255, 260
反应条件
(i) ZNH2, PCl3, AcOH, (ii) aq. HCl; Multistep reaction;
参考文献
Synthesis, , p. 479 - 480
