1: 4-methoxy-aniline With hydrogenchloride in water T=0 - 5°C; 2: With sodium tetrafluoroborate; sodium nitrite in water T=5°C; 0.166667 h; 3: diphenyldimethoxysilane With methanol; palladium diacetate T=25°C; Hiyama coupling; 6 h;
1: With 1,1'-bis-(diphenylphosphino)ferrocene; CuF(PPh3)3 in N,N-dimethyl-formamide T=40°C; 1 h; 2: With tetrabutyl ammonium fluoride in tetrahydrofuran; N,N-dimethyl-formamide T=20°C; 0.166667 h;
参考文献
Tomita, Daisuke; Wada, Reiko; Kanai, Motomu; Shibasaki, Masakatsu
Journal of the American Chemical Society, 2005 , vol. 127, # 12 p. 4138 - 4139
1: p-toluidine With hydrogenchloride in water T=0 - 5°C; 2: With sodium tetrafluoroborate; sodium nitrite in water T=5°C; 0.166667 h; 3: diphenyldimethoxysilane With methanol; palladium diacetate T=25°C; Hiyama coupling; 6 h;
