1-(4-甲氧基苯基)-1-庚酮合成路线 （共 23 条）
反应条件
pyrrolidine; 1,3-bis-(diphenylphosphino)propane; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide
T=115°C; Heck reaction; 6 h; Molecular sieve;
参考文献
Ruan, Jiwu; Saidi, Ourida; Iggo, Jonathan A.; Xiao, Jianliang
Journal of the American Chemical Society, 2008 , vol. 130, # 32 p. 10510 - 10511
反应条件
copper ferrite in 1,2-dichloro-ethane
T=80°C; Friedel-Crafts Acylation; 24 h;
参考文献
Parella, Ramarao; Naveen; Kumar, Amit; Babu, Srinivasarao Arulananda
Tetrahedron Letters, 2013 , vol. 54, # 13 p. 1738 - 1742
反应条件
5-hexyl-2,4,6-triaminopyrimidine; substituted barbituric acid aminopyridine-containing reagent; triphenylphosphine; [Rh(coe)2Cl]2; cyclohexylamine in 1,4-dioxane
T=150°C;
参考文献
Kim, Do-Won; Lim, Sung-Gon; Jun, Chul-Ho
Organic Letters, 2006 , vol. 8, # 14 p. 2937 - 2940
反应条件
hydrogenchloride; sodium sulfide in methanol
T=65°C; 60 h;
参考文献
Chapdelaine, Marc J.; Warwick, Paul J.; Shaw, Andrew
Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1218 - 1221
反应条件
4-methyl-pyridin-2-ylamine; anhydrous 4,4'-bipyridyl; 4-carboxyphenyldiphenylphosphine; [(C8H14)2RhCl]2 in phenol
T=150°C; 6 h;
参考文献
Chang, Duck-Ho; Lee, Dae-Yon; Hong, Boo-Sun; Choi, Jun-Hack; Jun, Chul-Ho
Journal of the American Chemical Society, 2004 , vol. 126, # 2 p. 424 - 425
反应条件
3-methyl-2-amino-pyridine; aniline; benzoic acid; Wilkinson's catalyst in toluene
T=130°C; 1 h;
参考文献
Jun, Chul-Ho; Lee, Dae-Yon; Lee, Hyuk; Hong, Jun-Bae
Angewandte Chemie (International Edition in English), 2000 , vol. 39, # 17 p. X3070-3072
反应条件
iron (III) acetylacetonate in tetrahydrofuran
T=-78°C;
参考文献
Scheiper, Bodo; Bonnekessel, Melanie; Krause, Helga; Fuerstner, Alois
Journal of Organic Chemistry, 2004 , vol. 69, # 11 p. 3943 - 3949
反应条件
1: 1-hexyl-triphenylphosphonium bromide With n-butyllithium; lithium iodide in tetrahydrofuran; hexane
0.333333 h; cooling;
2: 2-methoxy 5-cyanobenzene in tetrahydrofuran; hexane
T=50°C; 8 h;
参考文献
Taber, Douglass F.; Cai, Lisi
Journal of Organic Chemistry, 2005 , vol. 70, # 12 p. 4887 - 4888
反应条件
in anhydrous dichloroethane; methoxybenzene
参考文献
Sumitomo Chemical Company, Limited
Patent: US5235068 A1, 1993 ;
反应条件
pyrrolidine; CataCXium POMetB; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl acetamide
T=140°C; 4 h; Inert atmosphereMolecular sieve;
参考文献
Colbon, Paul; Ruan, Jiwu; Purdie, Mark; Xiao, Jianliang
Organic Letters, 2010 , vol. 12, # 16 p. 3670 - 3673
