1: With diphenyl-N,N-bis-((S,S)-1-naphthalen-2-yl-ethyl)phosphinamine; copper(ll) bromide in diethyl ether
T=-30°C; 3 h;
2: With ammonium chloride in diethyl ether; water
optical yield given as percent eeenantioselective reaction;
1: n-butyl-magnesium bromide With lithium tetrachloromanganate(II) in tetrahydrofuran
0.75 h; cooling;
2: With chloro-trimethyl-silane in tetrahydrofuran
T=-10°C; 0.333333 h;
3: (2E)-1-(acetyloxy)-3-phenylprop-2-enyl acetate in tetrahydrofuran
T=-10°C; Further stages.;
参考文献
Deshmukh, Madhukar B.; Jadhav, Sunil D.; Kadam, Shashikant V.
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2007 , vol. 46, # 6 p. 989 - 994
