3-甲基-2,3,4,9-四氢-1H-咔唑合成路线 （共 16 条）
反应条件
1: 78 percent / AgF / H2O
2: 87 percent / CO2 / dimethylsulfoxide; CH2Cl2; acetonitrile / -40 - 20 °C
3: 89 percent / aq. TiCl3; NH4OAc / acetone / 0.25 h / 20 °C
View Scheme
参考文献
Iwama, Tetsuo; Birman, Vladimir B.; Kozmin, Sergey A.; Rawal, Viresh H.
Organic Letters, 1999 , vol. 1, # 4 p. 673 - 676
反应条件
montmorillonite clay
1) 5 min 2) 5 min, 120 deg C;
参考文献
Bhattacharyya, P.; Jash, S. S.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1987 , vol. 26, # 1-12 p. 1177
参考文献
Plant; Rosser
Journal of the Chemical Society, 1928 , p. 2461
反应条件
T=40.9°C; Rate constant;
参考文献
McLean et al.
Journal of the Chemical Society, 1955 , p. 2519
参考文献
Pausacker; Schubert
Journal of the Chemical Society, 1949 , p. 1384,1388
反应条件
palladium on activated charcoal
T=270 - 280°C; 0.5 h;
参考文献
Luo, Jiann-Kuan; Castle, Raymond N.; Lee, Milton L.
Journal of Heterocyclic Chemistry, 1989 , vol. 26, p. 1213 - 1219
