2,3,5-三甲基苯酚合成路线 （共 124 条）
反应条件
1: 99.8 percent / 60percent NaH in oil / dimethylsulfoxide / 10 h / Ambient temperature 2: 72.5 percent / chlorosulfonic acid / CH2Cl2 / -10 - -5 °C 3: 1.) 4 N NaOH / 1.) acetone, 3 h, 2.) ethyl acetate View Scheme
参考文献
Fujino, Masahiko; Wakimasu, Mitsuhiro; Kitada, Chieko
Chemical & Pharmaceutical Bulletin, 1981 , vol. 29, # 10 p. 2825 - 2831
反应条件
dihydrogen peroxide; methyltrioxorhenium (VII) in acetic acid T=20°C; 2 h;
参考文献
Journal of Organic Chemistry, , vol. 59, # 26 p. 8281 - 8283
反应条件
titanium superoxide; dihydrogen peroxide; acetic acid in water T=50°C; 2 h;
参考文献
Dewkar, Gajanan K.; Shaikh, Tanveer M.; Pardhy; Kulkarni, Swati S.; Sudalai, Arumugam
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2005 , vol. 44, # 7 p. 1530 - 1532
反应条件
peracetic acid; sulfuric acid T=50°C; 0.5 h;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 57, # 4 p. 923 - 930,819 - 826
反应条件
Li2Mo2V10O31.6+10.6H2O; dihydrogen peroxide in acetone T=20°C; Yield given. Yields of byproduct given;
参考文献
Korenskii, V. I.; Skobeleva, V. D.; Kharchuk, V. G.; Kolenko, I. P.; Volkov, V. L.; et al.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 9 p. 1969 - 1975,1750 - 1754
反应条件
peracetic acid T=50°C; 0.25 h; Product distributionKineticsThermodynamic data;
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 22, # 11 p. 2071 - 2078
Zhurnal Organicheskoi Khimii, , vol. 22, # 11 p. 2306 - 2315
反应条件
sulfuric acid T=50°C; 0.5 h; effect of catalysts; MechanismThermodynamic data;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 57, # 4 p. 923 - 930,819 - 826
反应条件
1.1: NaH / tetrahydrofuran / 1 h / 0 °C 1.2: 92 percent / tetrahydrofuran / 3 h / 0 °C 2.1: chlorosulfonic acid / CH2Cl2 / 1 h / 0 °C View Scheme
参考文献
Fujino, Masahiko; Wakimasu, Mitsuhiro; Kitada, Chieko
Chemical & Pharmaceutical Bulletin, 1981 , vol. 29, # 10 p. 2825 - 2831
反应条件
sulfuric acid T=50°C; 0.5 h; effect of catalysts; MechanismThermodynamic data;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 57, # 4 p. 923 - 930,819 - 826
反应条件
Li2Mo2V10O31.6+10.6H2O; dihydrogen peroxide in acetone T=20°C; Yield given. Yields of byproduct given;
参考文献
Korenskii, V. I.; Skobeleva, V. D.; Kharchuk, V. G.; Kolenko, I. P.; Volkov, V. L.; et al.
J. Gen. Chem. USSR (Engl. Transl.), 1985 , vol. 55, # 9 p. 1969 - 1975,1750 - 1754
