2,5-二甲基-1-己烯合成路线 （共 22 条）
反应条件
in monofluoro-trichloromethane
T=-78°C; Irradiation1.) 140 deg C, benzene; 2.) -78 deg C, irradiation, CH2Cl2, thioxanthone; Yields of byproduct given;
参考文献
Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6660 - 6668
反应条件
in monofluoro-trichloromethane
T=-78°C; 12 h; Irradiation; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6660 - 6668
反应条件
in diethyl ether
T=0°C; Further byproducts given;
参考文献
Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 878 - 880
反应条件
dilithium tetrachlorocuprate in tetrahydrofuran
T=0°C; 3 h; Yield given;
参考文献
Beckwith, Athelstan L. J.; Moad, Graeme
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 1083 - 1092
反应条件
in monofluoro-trichloromethane
T=-78°C; 12 h; Irradiation1.) 0 deg C, CFCl3; 2.) -10 deg C, CFCl3; 3.) -20 deg C, CFCl3; 4.) -78 deg C, irradiation, CFCl3, azulene; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6660 - 6668
反应条件
in hexane
T=-21.6 - 4°C; other solvents (Et2O, THF), relative rate constants; E(activ.), ΔH(activ.); KineticsThermodynamic data;
参考文献
Schultz, Peter G.; Dervan, Peter B.
Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 878 - 880
反应条件
(4-cyclooctene-1-yl)(1,1,1,5,5,5-hexafluoro-2,4-acetylacetonato)nickel in m-xylene
T=120°C; 2 h; AutoclaveInert atmosphere; Catalytic behavior; Reagent/catalystTemperatureSolvent;
参考文献
Behr, Arno; Rentmeister, Nils; Seidensticker, Thomas; Vosberg, Jonas; Peitz, Stephan; Maschmeyer, Dietrich
Chemistry - An Asian Journal, 2014 , vol. 9, # 2 p. 596 - 601
反应条件
methanol; palladium
Hydrogenation;
参考文献
Salkind; Smagina
Zhurnal Obshchei Khimii, vol. 7, p. 473
Chem. Zentralbl., 1937 , vol. 108, # I p. 4490
反应条件
tri-n-butyl-tin hydride in decalin
T=60.2°C; 24 h; The ratio of hydrogen atom transfer rate vs the rate of ring opening.; Product distribution;
参考文献
Beckwith, Athelstan L. J.; Moad, Graeme
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 1083 - 1092
参考文献
Gostunskaja et al.
Doklady Akademii Nauk SSSR, 1956 , vol. 108, p. 473
Doklady Chemistry, 106-111<1956>273
