4,6-十烷二炔基-1,10-二醇合成路线 （共 10 条）
反应条件
ethanol; nickel T=20°C; P=73550.8 Torr; Hydrogenation;
参考文献
Paul; Tchelitcheff
Bulletin de la Societe Chimique de France, 1953 , p. 417,420
反应条件
copper(l) iodide; N,N,N',N,-tetramethylethylenediamine; oxygen in acetone
T=20°C; 3 h;
参考文献
Volchkov, Ivan; Sharma, Kamlesh; Cho, Eun Jin; Lee, Daesung
Chemistry - An Asian Journal, 2011 , vol. 6, # 8 p. 1961 - 1966
反应条件
copper(l) iodide; triethylamine; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride
T=60°C; Sonogashira reaction; 3 h;
参考文献
Pereira, Raquel; Iglesias, Beatriz; De Lera, Angel R
Tetrahedron, 2001 , vol. 57, # 37 p. 7871 - 7881
反应条件
1: With dicobalt octacarbonyl in dichloromethane
T=20°C; 1 h;
2: With boron trifluoride diethyl etherate in dichloromethane
T=20°C; Nicholas reaction; 3 h;
3: With ammonium cerium(IV) nitrate in acetone
T=0°C; 0.0833333 h; Further stages.;
参考文献
Diaz, David D.; Ramirez, Miguel A.; Martin, Victor S.
Chemistry - A European Journal, 2006 , vol. 12, # 9 p. 2593 - 2606
反应条件
propylamine; anhydrous 1-octyne; hydroxylamine; copper(l) chloride in ethanol
Ambient temperature;
参考文献
Montierth, John M.; DeMario, Dierdre R.; Kurth, Mark J.; Schore, Neil E.
Tetrahedron, 1998 , vol. 54, # 39 p. 11741 - 11748
反应条件
propylamine; hydroxylamine; copper(l) chloride in ethanol
Ambient temperature;
参考文献
Montierth, John M.; DeMario, Dierdre R.; Kurth, Mark J.; Schore, Neil E.
Tetrahedron, 1998 , vol. 54, # 39 p. 11741 - 11748
反应条件
copper(l) iodide; N,N,N',N,-tetramethylethylenediamine; oxygen in ethylene glycol dimethyl ether
T=55°C; Hay coupling;
参考文献
Rougeau, Laurent; Picq, Dominique; Rastello, Marie; Frantz, Yves
Tetrahedron, 2008 , vol. 64, # 40 p. 9430 - 9436
反应条件
copper(l) iodide; N,N,N',N,-tetramethylethylenediamine; oxygen in ethylene glycol dimethyl ether
T=55°C; Hay coupling;
参考文献
Rougeau, Laurent; Picq, Dominique; Rastello, Marie; Frantz, Yves
Tetrahedron, 2008 , vol. 64, # 40 p. 9430 - 9436
反应条件
copper(l) iodide; N,N,N',N,-tetramethylethylenediamine; oxygen in ethylene glycol dimethyl ether
T=55°C; Hay coupling;
参考文献
Rougeau, Laurent; Picq, Dominique; Rastello, Marie; Frantz, Yves
Tetrahedron, 2008 , vol. 64, # 40 p. 9430 - 9436
反应条件
1.1: 786 mg / n-Bu4NF / tetrahydrofuran / 2 h / 20 °C
2.1: 88 percent / Cu(OAc)2; pyridine / methanol / 4 h / Heating
3.1: [Co2(CO)8] / CH2Cl2 / 1 h / 20 °C
3.2: BF3*OEt2 / CH2Cl2 / 3 h / 20 °C
3.3: 63 percent / CAN / acetone / 0.08 h / 0 °C
View Scheme
参考文献
Diaz, David D.; Ramirez, Miguel A.; Martin, Victor S.
Chemistry - A European Journal, 2006 , vol. 12, # 9 p. 2593 - 2606
