1: With potassium hydrogencarbonate in water; N,N-dimethyl-formamide
T=100°C; 0.166667 h;
2: With bis(benzonitrile)palladium(II) dichloride in water; N,N-dimethyl-formamide
T=100°C; 24 h;
参考文献
Zhou, Chengxiang; Larock, Richard C.
Journal of Organic Chemistry, 2005 , vol. 70, # 10 p. 3765 - 3777
tris(dibenzylideneacetone)dipalladium (0) in toluene
T=90°C; 20 h;
参考文献
Itami, Kenichiro; Mineno, Masahiro; Muraoka, Nobuhiro; Yoshida, Jun-Ichi
Journal of the American Chemical Society, 2004 , vol. 126, # 38 p. 11778 - 11779
N-bromosuccinmide; dibenzoyl peroxide in tetrachloromethane
9 h; Heating;
参考文献
Rao, K. V. B.; Iyer, R. N.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1980 , vol. <B> 19, # 6 p. 504 - 507
1.1: 99 percent / Pd[P(t-Bu)3]2; Et3N / toluene / 80 °C
2.1: tetrahydrofuran; pentane / -78 - 0 °C
2.2: Pd(PPh3)4; CuI / tetrahydrofuran; pentane / 50 °C
2.3: 82 percent / 2,3-dichoro-5,6-dicyanobenzoquinone / tetrahydrofuran; pentane / 20 °C
3.1: 72 percent / Pd2(dba)3 / toluene / 20 h / 90 °C
View Scheme
参考文献
Itami, Kenichiro; Mineno, Masahiro; Muraoka, Nobuhiro; Yoshida, Jun-Ichi
Journal of the American Chemical Society, 2004 , vol. 126, # 38 p. 11778 - 11779
1.1: tetrahydrofuran; pentane / -78 - 0 °C
1.2: Pd(PPh3)4; CuI / tetrahydrofuran; pentane / 50 °C
1.3: 82 percent / 2,3-dichoro-5,6-dicyanobenzoquinone / tetrahydrofuran; pentane / 20 °C
2.1: 72 percent / Pd2(dba)3 / toluene / 20 h / 90 °C
View Scheme
参考文献
Itami, Kenichiro; Mineno, Masahiro; Muraoka, Nobuhiro; Yoshida, Jun-Ichi
Journal of the American Chemical Society, 2004 , vol. 126, # 38 p. 11778 - 11779
