hydrogen; sodium hydrogencarbonate; {W(CO)5Cl}(1-) in tetrahydrofuran T=150°C; P=4137.2 - 4395.8 Torr; 24 h; with various metal pentacarbonyl chlorides and alkal-metal salts and alkyl halides; Product distributionRate constant;
参考文献
Journal of the American Chemical Society, , vol. 109, # 11 p. 3330 - 3336
pyridine; osmium(III) chloride; dihydrogen peroxide in acetonitrile T=80°C; Oxidation; P=1500.15 Torr; 1.5 h; Title compound not separated from byproducts.;