other Radiation; benzyl isocyanate is dropped in He or in mixture of He and 40percent CF4 at 3 atm pressure, the material is expanded through a pulsed molecular beam valve and irradiated by perpendicular electron beam;
参考文献
Bradforth, Stephen E.; Kim, Eun Ha; Arnold, Don W.; Neumark, Daniel M.
Journal of Chemical Physics, 1993 , vol. 98, # 2 p. 800 - 810
→
反应条件
in neat (no solvent)
Kinetics; byproducts: MeNCO2H, HN2OMe; flowing afterglow-selected ion flow tube instrument, 300 K, helium buffer gas pressure 0.5 Torr, flow 225 cm**3;
参考文献
Sheldon, John C.; O'Hair, Richard A. J.; Downard, Kevin M.; Gronert, Scott; Krempp, Michele; et al.
Australian Journal of Chemistry, 1995 , vol. 48, # 2 p. 155 - 166
hydroperoxide anion in gaseous matrix
T=26.9°C; in a flowing afterglow system (flow rector affixed to a quadrupole mass spectrometer); Rate constantProduct distribution;
参考文献
Bowie, John H.; DePuy, Charles H.; Sullivan, Sally A.; Bierbaum, Veronica M.
Canadian Journal of Chemistry, 1986 , vol. 64, p. 1046 - 1050
