4’-(三氟甲硫基)苯乙酮合成路线 （共 6 条）
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide T=130°C; 24 h; Inert atmosphereSealed tubeGlovebox;
参考文献
Tetrahedron, , vol. 69, # 48 p. 10262 - 10266
反应条件
[2,2']bipyridinyl; [Cu(I)(CH3CN)4]PF6; potassium carbonate in diethylene glycol dimethyl ether T=35°C; Schlenk techniqueInert atmosphere;
参考文献
Shao, Xinxin; Wang, Xueqiang; Yang, Tao; Lu, Long; Shen, Qilong
Angewandte Chemie - International Edition, 2013 , vol. 52, # 12 p. 3457 - 3460
Angew. Chem., 2013 , vol. 125, # 12 p. 3541 - 3544,4
反应条件
1: p-acetylbenzenediazonium tetrafluoroborate With copper(I) isothiocyanate; sodium isothiocyanate; caesium carbonate in acetonitrile T=20°C; 0.166667 h; Inert atmosphere; 2: (trifluoromethyl)-trimethylsilane in acetonitrile T=20°C; 16 h;
参考文献
Danoun, Gregory; Bayarmagnai, Bilguun; Gruenberg, Matthias F.; Goossen, Lukas J.
Chemical Science, 2014 , vol. 5, # 4 p. 1312 - 1316
反应条件
in acetonitrile 15 h; Inert atmosphereSealed tubeHeating;
参考文献
Weng, Zhiqiang; He, Weiming; Chen, Chaohuang; Lee, Richmond; Tan, Davin; Lai, Zhiping; Kong, Dedao; Yuan, Yaofeng; Huang, Kuo-Wei
Angewandte Chemie - International Edition, 2013 , vol. 52, # 5 p. 1548 - 1552
Angew. Chem., 2013 , vol. 125, # 5 p. 1588 - 1592
反应条件
(i) Mg, EtOH, CCl4, (ii) aq. H2SO4, AcOH, (heating); Multistep reaction;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 31, p. 1315 - 1320,1219 - 1223
反应条件
in benzene Irradiationother solvent; Quantum yield;
参考文献
Journal of Organic Chemistry, , vol. 46, # 26 p. 5431 - 5434
