[1,1'-双(二苯基膦基)二茂铁]二氯化钯合成路线 （共 15 条）
反应条件
in acetonitrile 4 h; Heating / reflux;
参考文献
WO2007/29031 A1, ;
Page/Page column 6 ;
反应条件
in tetrahydrofuran; ethanol inert atmosphere, dry solvents; addn. of dppf in THF to soln. of Pd-compd. in EtOH, pptn., stirring (1 h); removal of solvent, washing (water), drying (80°C, 12 h);
参考文献
Housecroft, Catherine E.; Owen, Steven M.; Raithby, Paul R.; Shaykh, Bilal A. M.
Organometallics, 1990 , vol. 9, p. 1617 - 1623
反应条件
in benzene (Ar); addn. of soln. of Pd(PhCN)2Cl2 in benzene to soln. of Fe(C5H4PPh2)2 in benzene; pptn. for a few minutes; stirring overnight; crystn., filtration, washing with benzene, drying under vac.;
参考文献
Gusev, Oleg V.; Peganova, Tat'yana A.; Kalsin, Alexander M.; Vologdin, Nikolai V.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Tsvetkov, Aleksey V.; Beletskaya, Irina P.
Organometallics, 2006 , vol. 25, # 11 p. 2750 - 2760
反应条件
in dichloromethane-d2 under N2 atm. to soln. Pd(CH2=CHCHO)(dppf) in CD2Cl2 MeOSO2C6H4-p-NO2 was added at room temp. and stirred for 12 h; identified by NMR;
参考文献
Organometallics, , vol. 22, # 26 p. 5468 - 5472
反应条件
in further solvent(s) under N2 atm. to soln. Pd(CH2=CHCHO)(dppf) in C2D4Cl2 MeOMs was added atroom temp. and heated to 60°C; identified by NMR;
参考文献
Organometallics, , vol. 22, # 26 p. 5468 - 5472
反应条件
in acetone to suspn. of Pd-complex in acetone Fe-complex was added, stirred at roomtemp. for 2 h under inert atm.; vol. was reduced in vac., Et2O was added, stirred for 10 min, filtered, washed with Et2O, dried under vac.;
参考文献
Colacot, Thomas J.; Qian, Hu; Cea-Olivares, Raymundo; Hernandez-Ortega, Simon
Journal of Organometallic Chemistry, 2001 , vol. 637-639, p. 691 - 697
反应条件
in chloroform-d1 byproducts: acetone; slowly decompd. in CDCl3 soln.;
参考文献
Organometallics, , vol. 27, # 15 p. 3978 - 3985
反应条件
in dichloromethane (Ar), stirring a soln. of palladium complex and silver salt in CH2Cl2 atroom temp. for 2 h in the dark;
参考文献
Journal of Organometallic Chemistry, , vol. 658, # 1-2 p. 159 - 168
反应条件
in dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, pptn., filtered, dried in vac.;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
反应条件
in not given mixing;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 11 p. 1103 - 1104
