C2H6S*C18H15OP*Cl3ORe in ethylene glycol dimethyl ether T=80°C; Meyer-Schuster rearrangement; 24 h;

MoVIO2(acetylacetone)2; [(PPh3)AuCl]; silver trifluoromethanesulfonate in toluene T=20°C; Meyer-Schuster rearrangement; 1 h;

palladium anchored polystyrene in diethyl ether T=25°C; P=1551.4 Torr; 36 h;

暂无反应条件数据

[Rh(rac-BINAP)]BF4 in dichloromethane T=80°C; 1 h;

[Rh((R)-BINAP)]BF4 in dichloromethane T=25°C; 14 h;

1: With carbon tetrabromide in dichloromethane T=0°C; 0.166667 h; 2: With triphenylphosphine in dichloromethane T=0 - 20°C;

4-methylpyridine 1-oxide; (IPr)AuCl; bis-(trifluoromethylsulphonyl)amine; AgNTf2 in dichloromethane T=20°C; 24 h;

[Rh(OH)(cycloocta-1,5-diene)]2; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in 1,4-dioxane; water T=20 - 60°C; 3 h; Inert atmosphere; stereoselective reaction;

1: 82 percent / N,N-dimethylaminopyridine (DMAP), Et3N / CH2Cl2 / 3 h / Ambient temperature 2: 99 percent / H2, quinoline / Pd (5percent on BaSO4) / 1.5 h 4: 74 percent / H2 / Pd (10percent on C) / methanol / 2 h / 760 Torr 5: 1.) boron trifluoride 2.) aq. sodium hydrogen carbonate / 1.) AcOH, CH2Cl2, 20 deg C, 1.5 h 2.) 15 min 6: 74 percent / Et3N, m-chloroperbenzoic acid / diethyl ether / 20 h / Ambient temperature View Scheme