(CD3COCD3)D(1+) in gas T=57.9°C; experiment conditions: NBS pulsed ion cyclotron resonance; probability of a reactive H/D exchange encounter for the deuteronated ion as a function of the Gibbs free-energy change of the (endoergic) deuteron transfer reaction; Rate constantMechanismThermodynamic data;
参考文献
Journal of the American Chemical Society, , vol. 103, # 13 p. 3641 - 3647
in gas Kinetics; reaction carried out in a transverse flow reactor consisted of a stainless steel vacuum-tight vessel containing Teflon box; detected by infrared transient absorption spectroscopy;
参考文献
Decker, Brian K.; Macdonald, R. Glen
Journal of Physical Chemistry A, 2001 , vol. 105, # 28 p. 6817 - 6825
