dilithioferrocene-(CH3)2NC2H4N(CH3)2 in hexane
hexane, -20°C;
参考文献
Whittell, George R.; Partridge, Benjamin M.; Presly, Oliver C.; Adams, Christopher J.; Manners, Ian
Angewandte Chemie - International Edition, 2008 , vol. 47, # 23 p. 4354 - 4357
hydrazine in tetrahydrofuran
T=23°C; 0.25 h; Inert atmosphere;
参考文献
Kalutarage, Lakmal C.; Heeg, Mary Jane; Martin, Philip D.; Saly, Mark J.; Kuiper, David S.; Winter, Charles H.
Inorganic Chemistry, 2013 , vol. 52, # 3 p. 1182 - 1184
Cueilleron, J.
Bulletin de la Societe Chimique de France, 1945 , vol. 12, # 5 p. 88 - 89
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Gmelin Handbook: Ni: MVol.AI, 10.1, page 603 - 609
in neat (no solvent)
byproducts: CH2CHCN, P(C6H5)3; thermal decompn. in closed tube;;
参考文献
Schrauzer, G. N.
Journal of the American Chemical Society, 1960 , vol. 82, p. 1008 - 1009
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反应条件
poly(vinylpyrrolidone) in ethylene glycol
byproducts: N2; N2H4*H2O was added dropwise under vigorous stirring to a soln. of NiCl2*6H2O and PVP in HOCH2CH2OH at room temp., the mixt. was refluxed for 5 h; Ni(NH3)6Cl2 was obtained as nanotubes of 30-40 nm in diameter, ca. 2μm in length, 3-5 nm thick; ppt. was sepd. by centrifugation, washed with EtOH; X-ray diffraction study, TEM and HRTEM;
参考文献
Guo, Lin; Liu, Chenmin; Wang, Rongming; Xu, Huibin; Wu, Ziyu; Yang, Shihe
Journal of the American Chemical Society, 2004 , vol. 126, # 14 p. 4530 - 4531
