反应条件
H2 in n-heptane
Ni complex refluxed with 1.5 molar excess of HC2C(=CH2)CH3 in heptane or octane under N2 or H2 with IR monitoring, cooled in inert atmosphere, treated with equimolar amts. of Fe complex in refluxing heptane under H2for 40 min; filtered under N2, evapd. (vac.), dissolved in CHCl3, chromd. (SiO2, light petroleum/Et2O), crystd. (satd. heptane/CHCl3);
参考文献
Marchino, Maria Luisa Nanni; Sappa, Enrico; Lanfredi, Anna Maria Manotti; Tiripicchio, Antonio
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 1541 - 1546