in water
10 g/l Ni(2+) soln., pH 1.5-3.9 at 24-100°C, form of product is powder;
参考文献
Kryukova, V. N.; Tseft, A. L.
Vestnik Akademii Nauk Kazakhskoi SSR, 1960 , vol. 16, # 11 p. 24 - 33
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Gmelin Handbook: Ni: MVol.AI, 10.2, page 609 - 616
Botts, E. D.; Krauskopf, F. C.
Journal of Physical Chemistry, 1927 , vol. 31, p. 1404 - 1409
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Gmelin Handbook: Ti: MVol., 3.5, page 189 - 199
in ethylene glycol
Ni and Cu nitrates (molar ratio 80:20) mixed with ethylene glycol at room temp. under magnetic agitation; heated to 196°C for 4 h; solid sepd. by centrifugation; washed with acetone; dried in air; detd. by X-ray and electron diffraction;
参考文献
Bonet; Grugeon; Dupont; Herrera Urbina; Guery; Tarascon
Journal of Solid State Chemistry, 2003 , vol. 172, # 1 p. 111 - 115
in gaseous matrix
byproducts: C5H5; Irradiation (UV/VIS); multi-photon dissociation of Ni-compd. at 266 nm; carrier gas Ar or Ar+He mixture; supersonic expansion;
参考文献
Kawamoto, Yasunobu; Honma, Kenji
Chemical Physics Letters, 1998 , vol. 298, # 1-3 p. 227 - 232
→
反应条件
in neat (no solvent)
Kinetics; reaction of high-purity H2 (4 MPa) with LaNi5 at 300°C for 10 days; monitored by temperature programmed desorption;
参考文献
Zhu, H. Y.; Wu, J.; Wang, Q. D.
Journal of Alloys and Compounds, 1992 , vol. 185, p. 1 - 6