Chandraiah, U; Murthy, C. P.; Kandlikar, Sushama
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1989 , vol. 28, # 2 p. 162 - 163
→
反应条件
hydroxide
Kinetics; byproducts: H2O;
参考文献
Chandraiah, U; Murthy, C. P.; Kandlikar, Sushama
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1989 , vol. 28, # 2 p. 162 - 163
→
反应条件
hydroxide
Kinetics; byproducts: H2O;
参考文献
Chandraiah, U; Murthy, C. P.; Kandlikar, Sushama
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical & Analytical, 1989 , vol. 28, # 2 p. 162 - 163
→
反应条件
in neat (no solvent)
byproducts: MgCl2; vac. or N2 filled glove box; mixt. grinding, heating in evac. sealed quartz ampoule at 850°C for 10 h, cooling to room temp., grinding; powder trituration with MeOH or H2O;
参考文献
Fitzmaurice, Jonathan C.; Hector, Andrew L.; Parkin, Ivan P.; Rowley , Adrian T.
Phosphorus, Sulfur and Silicon and the Related Elements, 1995 , vol. 101, # 1-4 p. 47 - 56
→
反应条件
in water
pyrolysis of mist of 0.05 M aq. sucrose and 0.05 M Ni-salt at 1073 K under Ar, stainless steel reactor, electric heater; gas stream after the reaction was collected in H2O, sepd. by a magnet, both portions were filtered off, washed with H2O, dried at 343 K overnight; Ni was formed as Ni-C (9:1) composite;
in neat (no solvent)
High Pressure; treatment of ZrVNiH2.8 with nitrogen (10 MPa) at 973 K for 10 h;
参考文献
Shilkin
Russian Journal of General Chemistry, 2002 , vol. 72, # 8 p. 1167 - 1169
→
反应条件
in neat (no solvent)
byproducts: MgCl2; High Pressure; mixt. loaded into autoclave; after pumping to residual pressure of about1 Pa at 20°C over 30 min, charged with NH3 to pressure of 0.6-0. 8 MPa; left for 30 min; heated to 450°C; held for 3 h; cooled to about 20°C; heated again; drawn from reactor in inert at./; monitored by X-ray diffraction;
in neat (no solvent)
High Pressure; loaded into autoclave; after pumping to residual pressure of about 1 Pa at 20°C over 30 min, charged with NH3 to pressure of 0.6-0.8 MPa;left for 30 min; heated to 300°C; held for 3 h; cooled to about 20°C; heated again; drawn from reactor in inert at./; monitored by X-ray diffraction;
