PF3 in 2-methyl cyclohexane
absence of air and moisture; condensing Ni-vapour into methylcyclohexanecontg. excess of PF3 and cycloheptatriene (-130°C); IR and mass spectroscopy;
参考文献
Timms, Peter L.; Turney, Terence W.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1976 , p. 2021 - 2025
in neat (no solvent)
High Pressure; treating Ni-powder (prepd. by thermal decompn. of Ni-oxalate in N2- or H2-stream) in rotary autoclave (Cu-impeller) with PF3 (350 atm) for 42 h at 100 °C;; distilling off PF3 at -100 °C, further react. with PF3 for 16 h at 100 °C and 180 atm;;
