Gmelin Handbook: B: B-Verb.8, 11.2.3, page 167 - 173
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Washburn, R. M.; Billig, F. A.
Patent: US3311662 , 1967 ;
C.A., 1967 , vol. 67, p. 11577
in neat (no solvent) Kinetics; reaction in a diffusion flame above 247°C, H2 as a carrier gas; mechanism discussed;; condensation of the products at -196°C;;
参考文献
Canadian Journal of Chemistry, , vol. 30, p. 473 - 481
in neat (no solvent) byproducts: Cl2; react. starting at 120 °C, react. at higher temp. with detonation; formation of a grey-black compound with composition PN impured with Cl2;;
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Renaud, P.
Bulletin de la Societe Chimique de France, 1933 , vol. 53, p. 692 - 697
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Gmelin Handbook: P: MVol.C, 243, page 555 - 557
in diethylene glycol dimethyl ether byproducts: H2; further intermediate: NaSiH3; under N2, dispersion of sodium reacts with SiH4 at 100°C, concd. in vacuo at 30°C, C4F9SO3SiH3 added at -60°C, stored at this temp. for 10 min, warmed to 40°C; volatiles removed over 3 h in vacuo, SiH4 removed; GC;
in diethylene glycol dimethyl ether byproducts: H2; further intermediate: NaSiH3; under N2, dispersion of sodium reacts with SiH4 at 100°C, soln. of PhSO3H added dropwise at -40°C; volatiles removed at room temp. in vacuo, SiH4 removed; GC;
in tetrahydrofuran byproducts: NaCl; absence of air and moisture; slow addn. of 1 equiv. Ga-compd. to naphthalenide soln. (prepd. by stirring equimolar amts. of Na and naphthalenefor 18 h), stirring (-78°C, 18 h), slow warming to room temp., stirring for 14-19 h; solvent removal (vac.), extn. into C6H6, chromy. (Bio-Beads), recrystn.(pentane/C6H6=5:1 v/v); elem. anal.;
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Beachley Jr.; Noble, Matthew J.; Allendoerfer, Robert D.
Journal of Organometallic Chemistry, 1999 , vol. 582, # 1 p. 32 - 39
in methanol; benzene byproducts: Na(C2H5OC(O)CHC(O)CH3); N2 atmosphere; addn. of soln. of Sn(etac)2 in C6H6 to soln. of Na in MeOH (Sn : Na = 1 : 2, stirring, room temp.), stirring (0.5 h; pptn.); filtration, washing (MeOH, benzene), drying (vac.); elem. anal.;
参考文献
Wakeshima, Ikuko; Suzuki, Toshitaka; Takemoto, Akihiko; Kijima, Ichiro
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1997 , vol. 27, # 5 p. 787 - 796
