反应条件
in neat (no solvent, solid phase) stoich. proportions (Ca:Co=1.24:1.62) of CaO2, Co, Co3O4 and solid NaClO4 mixed in ball mill (4 h), pressed into pellets, then placed inside reacor for self-propagating high-temp. synthesis and ignited under O2 (ignition period 2 s), 460-988°C; XRD;
参考文献
Lin, Sidney; Selig, Jiri
Journal of Alloys and Compounds, 2010 , vol. 503, # 2 p. 402 - 409