反应条件
magnesium in tetrahydrofuran byproducts: MgCl2; (1) vinyl chloride bubbled through a suspn. of Mg in an inert atmosphere, the react. initiated with 1,2-dibromoethane and performed at 55-60°C (25-30°C by the end); (2) a soln. of GeCl4 added dropwise at temp. not exceeding 30°C; kept at 20-30°C for 6 h; treated with H2O, the aq. layer sepd., the org. layer washed (H2O), distd. fractionally to give mixts.;
参考文献
Zhun'; Sbitneva; Kisin; Chernyshev
Russian Journal of General Chemistry, 2004 , vol. 74, # 7 p. 1130 - 1131
