反应条件
in toluene Al(CH3)3 soln. added to (C5H4(CH3))(C5H5)TiCl2 (Ar) contg. impurity of (C5H5)2TiCl2, stirred for 40 h at room temp., solvent and Al(CH3)2Cl removed (vac.), dissolved in toluene, Al(CH3)3 soln. added, stirred for 12 h; solvent removed (vac.), , extd. (hexane), concd., cooled to -50°C, powder washed with hexane, dried (vac.);
参考文献
Ott, Kevin C.; deBoer, E. J. M.; Grubbs, Robert H.
Organometallics, 1984 , vol. 3, p. 223 - 230
