1: trimethylaluminum; 6,10,14-Trimethyl-pentadec-1-yne With zirconocene dichloride in 1,2-dichloro-ethane 2: With n-butyllithium in tetrahydrofuran 3: formaldehyd in tetrahydrofuran Further stages.;
1: trimethylaluminum With 1,4-diaza-bicyclo[2.2.2]octane in toluene T=0°C; 2: 4-fluorobenzaldehyde With [(R)-1,1'-binaphthyl-2,2'-diyldioxy]{bis[(S)-(1-phenylethyl)]amino}phosphine; bis(acetylacetonate)nickel(II) in tetrahydrofuran T=5°C; 3 h; Title compound not separated from byproducts;
参考文献
Raluy, Eva; Dieguez, Montserrat; Pamies, Oscar
Tetrahedron Asymmetry, 2009 , vol. 20, # 13 p. 1575 - 1579
