titanium tetrachloride in dichloromethane
T=-78°C; 3 h; other temperatures, time and solvents; var. homopropargyl alkohols; Product distributionMechanism;
参考文献
Ewing, James C.; Ferguson, Gregory S.; Moore, Douglas W.; Schultz, Frederick W.; Thompson, David W.
Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2124 - 2128
1: With zirconocene dichloride in dichloromethane; water
T=-23°C; 0.25 h;
2: With iodine in tetrahydrofuran; dichloromethane; water
T=-23°C; 0.166667 h; Further stages.;
参考文献
Yang, Fanglong; Newsome, Jeffery J.; Curran, Dennis P.
Journal of the American Chemical Society, 2006 , vol. 128, # 43 p. 14200 - 14205
